Search results for: NAPOINY FE-CR-MN
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Charakterystyka kawitacyjna laserowo obrabianych napoin Fe-Cr-Mn
PublicationPrzedstawiono badania odporności kawitacyjnej napoin Fe-Cr-Mn w dwóch przypadkach: bez dodatkowej obróbki powierzchniowej oraz po przetapianiu powierzchni napoiny wiązką lasera CO2 o mocy 1000W. Oceniano głębokość i stopień umocnienia warstwy wierzchniej.
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Effect of laser heating on cavitation behaviour of Fe-Cr-Mn coating.
PublicationW pracy przedstawiono badania odporności kawiracyjnej napoiny Fe-Cr-Mn po obróbce laserowej polegającej na przetapianiu napoiny wiązką lasera CO2 o mocy 1000W oraz jej nagrzewaniu w stanie stałym. Rezultaty badań wskazują,że po każdym rodzaju obróbki występuje inna podatność obrobionej powierzchni do odkształceń plastycznych pod działaniem obciążeń kawitacyjnych.
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Concentrations and loads of metals (V, Cr, Mn, Fe, Cu, Zn, As, Rb, Y, Zr) from the cliff erosion to the Gulf of Gdansk
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TEM data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe
Open Research DataThis Dataset include presentation of summarized TEM investigation of (Mn,Co,Fe,Ni,Cr)3O4 high-entropy spinel oxide prepared in the form of a ~ 500 nm thin film utilising a facile spray pyrolysis technique. The structural and electrical properties of the layers were characterised after exposure to temperatures in the range of 400–900 ◦C. The as-deposited...
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SEM/EDX data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe
Open Research DataThis Data set include SEM and EDX results of (Mn,Co,Fe,Ni,Cr)3O4 high-entropy spinel oxide prepared in the form of a ~ 500 nm thin film utilising a facile spray pyrolysis technique. The structural and electrical properties of the layers were characterised after exposure to temperatures in the range of 400–900 ◦C. The as-deposited layers were amorphous,...
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Total electrical conductivity data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe
Open Research DataThis dataset includes electrical conductivity measurements results measured by van der pauw technique up to 900oC.
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XRD data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe, annealed in a range from 400 to 900oC
Open Research DataDataset include collected XRD data of (Cr,Fe,Mn,Co,Ni)3O4 high-entropy spinel oxide thin films deposited by spray pyrolysis technique on amorphous SiO2 substrates and annealed from 400 to 900oC. Samples were prepared in the form of a ~ 500 nm thin film utilising a facile spray pyrolysis technique. The structural and electrical properties of the layers...
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Spinels in the Cu-Mn-(Fe, Ni, Zn, Cr)-O system: synthesis, studies of structure, physicochemical properties, and operando electrocatalytic activity
ProjectsProject realized in Katedra Inżynierii Materiałów Funkcjonalnych WETI according to UMO-2022/45/N/ST5/03627 agreement from 2023-01-17
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Coastal cliff erosion as a source of toxic, essential and nonessential metals in the marine environment
PublicationDue to the rising environmental awareness, emissions and releases of pollutants, including metals, have been considerably reduced in the last decades. Therefore, the remobiliza-tion of natural and anthropogenic contaminants is gaining importance in their biogeochemical cycle. In the marine coastal zone, this process occurs during the erosion of a shore, especially the most vulnerable cliffs. The research was conducted in the...
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Methods of Assessment of Metal Contamination in Bottom Sediments (Case Study: Straszyn Lake, Poland)
PublicationThe concentrations of six metals (Zn, Cu, Pb, Ni, Cr, and Cd) were investigated in bottom sediments of Straszyn Lake (North Poland). This study was designed to determine a total content of metals and to assess their mobility and bioavailability. The sequential extraction was used to fractionate metals into five fractions: exchangeable, bound to carbonates, bound to Fe–Mn oxides, bound to organic matter, and residual. The evaluation...
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Application of INAA and ETAAS techniques for human samples analysis in evaluation of the impact of Gdansk Phosphatic Fertilizer Plant on its workers
PublicationW pracy przedstawiono wyniki badań wpływu Gdańskich Zakładów Nawozów Fosforowych na zdrowie pracowników. Oznaczano stężenia (techniką INAA) Al, As,Au, Br, Ca, Cl, Cu, Dy, I, In, K, La, Mg, Mn, Mo, Na, S, Sb, Sm, Ti, U, V,W, Zn we włosach, paznokciach i filtrach z pyłem zebranych od 21 pracowników fabryki oraz 5 osób z grupy kontrolnej nie związanej z zakładem. Ponadto oznaczono Cd, Cr, Cu, Fe, Mo, Ni i Zn w moczu przy użyciu...
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Investigation on the Sources and Impact of Trace Elements in the Annual Snowpack and the Firn in the Hansbreen (Southwest Spitsbergen)
PublicationWe present a thorough evaluation of the water soluble fraction of the trace element composition (Ca, Sr, Mg, Na, K, Li, B, Rb, U, Ni, Co, As, Cs, Cd, Mo, Se, Eu, Ba, V, Ge, Ga, Cr, Cr, P, Ti, Mn, Zr, Ce, Zn, Fe, Gd, Y, Pb, Bi, Yb, Al, Nb, Er, Nd, Dy, Sm, Ho, Th, La, Lu, Tm, Pr, Tb, Fe, In, Tl) and their fluxes in the annual snowpack and the firn of the Hansbreen (a tidewater glacier terminating in the Hornsund fjord, southwest...
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Corrosion and hydrogen intake for some Cr-Mn steels in liquid hydrocarbons
PublicationStal 34HNM i 26H2MF, poddana różnym obróbkom cieplnym wykazała skłonność do korozji naprężeniowej przy pomiarach ze stałą szybkością rozciągania (10-6s-1) i pomiarach niskocyklowego zmęczenia, wykonanych w paliwie kotłowym. Mechanizm korozji naprężeniowej określono jako kruchość wodorowa, co zostało potwierdzone w pomiarach pochłaniania wodoru z tych środowisk. Jako możliwe źródła wnikania wodoru do stali omówiono procesy korozyjne,...
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Phytoavailability of potentially toxic elements from industrially contaminated soils to wild grass
PublicationTopsoil and grass samples from 14 sites located in different distances from three copper mining factories and a copper smelter were collected in Srednogorie, Bulgaria. The paper discusses results of studies on the mobility of potentially toxic elements (As, Cd, Cr, Cu, Mn, Ni, Pb, Zn) from contaminated soils to wild grass Cynodon dactylon in terms of transfer (TF: soil to plant) and phytoavailability (PF: EDTA (ethylenediaminetetraacetic...
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The Impact of Material Selection on Durability of Exhaust Valve Faces of a Ship Engine – A Case Study
Publicationwo alloys were used in order to extend the service life of marine engine exhaust valve head. Layers of cobalt base alloys were made of the powders with with chemical composition as follow: the layer marked L12; C-1,55%; Si-1,21%; Cr-29,7%; W-9%; Ni-2%; Mo<0,01%; Fe-1,7%; Co-54,83% and the layer marked N; C-1,45%; Co-38,9%; Cr-24,13%; Ni-10,43%; W-8,75%; Fe-7,64%; Mo-7,56%; Si-2,59%. Base metal was valve steel after heat treatment....
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Evaluation of structural and electrical properties of multicomponent spinel oxide thin films deposited via spray pyrolysis technique
PublicationThis work reports the preparation of (Mn,Co,Fe,Ni,Cr)3O4 high-entropy spinel oxide in the form of a ~ 500 nm thin film utilising a facile spray pyrolysis technique. The structural and electrical properties of the layers were characterised after exposure to temperatures in the range of 400–900 ◦C. The as-deposited layers were amorphous, and crystallised upon heat treatment at 500 ◦C. Microstructural analyses proved a homogeneous...
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Distribution and removal efficiency of heavy metals in two constructed wetlands treating landfill leachate
PublicationThe results of heavy metals (Fe, Mn, Zn, Ni, Cu, Cr, Pb, Cd) removal and partitioning between aqueous and solid phases at two wetlands (TWs) treating municipal landfill leachates are presented. One of the TWs is a surface flow facility consisting of 10 ponds. The other TW is a newly constructed pilot-scale facility consisting of three beds with alternately vertical and horizontal sub-surface flow. The metals concentrations were...
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Assessment of metal removal in a surface flow constructed wetland treating landfill leachate
PublicationThe study concerns heavy metal retention and transformation processes in a free water surface constructed wetland treating landfill leachate in a temperate climate. The total effectiveness of heavy metals removal in the analyzed CW was evaluated basing on heavy metals inflow and outflow concentrations. The concentrations of eight heavy metals (Fe, Mn, Zn, Pb, Ni, Cu, Cr, Cd) in landfill leachate (LL) and sediments were measured....
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Remediation of soils on municipal rendering plant territories using Miscanthus × giganteus
PublicationPhytoremediation, as a cost-effective, highly efficient, environmentally friendly, and green approach, gained attention to the removal of metals, including heavy metals, from contaminated soils. The toxic nature of heavy metals can have an adverse effect on human health and the ecosystem, and their removal remains a worldwide problem. Therefore, in this study, a field experiment was carried out to evaluate the potential of Miscanthus × giganteus...
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Assessment of the Bulgarian Wastewater Treatment Plants’ Impact on the Receiving Water Bodies
PublicationDeterioration of water quality is a major problem world widely according to many international non-governmental organizations (NGO). As one of the European Union (EU) countries, Bulgaria is also obliged by EU legislation to maintain best practices in assessing surface water quality and the efficiency of wastewater treatment processes. For these reasons studies were undertaken to utilize ecotoxicological (Microtox®, Phytotoxkit...
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Mineral Composition of Dietary Supplements-Analytical and Chemometric Approach
PublicationThere is a lack of data on the actual composition and effectiveness of beetroot-based dietary supplements. The research aimed to determine the profile of 22 elements (Na, K, Ca, Mg, P, Fe, As, Se, Zn, Cu, Ag, Co, Ni, Mo, Al, Mn, Sr, Cr, Ba, Li, Pb, Cd) in beetroot and its supplements by the microwave plasma atomic emission spectrometry (MP-AES) method. The analytical procedure was optimised and validated. The composition of both...
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Determination of metal content in sewage sludge and sewage sludge ash to find opportunities to use them in the construction industry
PublicationSewage sludge management is becoming an increasing problem in developed and developing countries. Due to their physicochemical properties (mainly high content of heavy metals) a safe method of utilization is sought. Considering environmental protection, energy recycling, reduction in use of the raw materials and the possibility of immobilization hazardous substances, the use of ashes in building materials becomes a very good way...
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Heavy Metals in a High Arctic Fiord and Their Introduction with the Wastewater: A Case Study of Adventfjorden-Longyearbyen System, Svalbard
PublicationLongyearbyen is the largest settlement on Svalbard archipelago, with 2400 permanent residents and approximately 150,000 tourists visiting every year. The city annually releases approximately 285,000 m3 of untreated wastewater to the nearby Adventfjorden. To date, the environmental impact of this continuous input has been studied mainly regarding the sediments and benthic fauna in the fiord. Here, we present results from a study...
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Synthesis, structure and physical properties of Ru ferrites: BaMRu5O11 (M= Li and Cu) and BaM'2Ru4O11 (M'=Mn, Fe and Co)
PublicationW pracy opisano syntezę, strukturę i właściwości fizyczne pięciu nowych związków z rodziny ferrytów na bazie Ru, których wzór chemiczny jest BaMRu5O11 (M = Li, Cu) i BaM'2Ru4O11 (M' = Mn, Fe, Co).
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Wpływ pH na ługowanie zwiercin łupkowych roztworami wodnymi
PublicationZwierciny wytworzone podczas poszukiwania węglowodorów w formacjach łupkowych mogą zawierać metale ciężkie i radionuklidy. Mając na uwadze zagospodarowanie zwiercin, wykonano badanie ich ługowania metodą statyczną, stosując roztwory wodne o różnych pH regulowanych HNO3 i KOH. Charakterystykę chemiczną zwiercin z otworu z Basenu Bałtyckiego przeprowadzono metodą rentgenowskiej analizy fluorescencyjnej, natomiast...
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Do You Know What You Drink? Comparative Research on the Contents of Radioisotopes and Heavy Metals in Different Types of Tea from Various Parts of the World
PublicationThe aim of this study was to assess the potential health risks of radioactive elements and heavy metals ingested through the consumption of various types of tea imported to the Polish market (black, green, red, oolong and white). The concentrations [Bq/kg] of radionuclides (40K, 137Cs, 226Ra, 210Pb and 228Th) in tea leaves before and after brewing were measured using γ-ray spectrometry with high-purity germanium (HPGe). The concentrations...
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Review of cigars and cigar-type products as potential sources of consumer exposure to heavy metals
PublicationThe popularity of cigars, growing since 1993, has not gone hand in hand with the increased interest of researchers in these products. Although the literature widely describes the harmfulness of tobacco and the content of toxic substances in tobacco products, the topic is often treated selectively as relating primarily to cigarettes and rarely extends to other products of the broadly defined tobacco industry. However, there is no...
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Rainwater chemistry composition in Bellsund: Sources of elements and deposition discrepancies in the coastal area (SW Spitsbergen, Svalbard)
PublicationDiscrepancies in rainfall chemistry in Bellsund were found to be influenced by the orographic barrier and related to the variability in the inflow of air masses as well as to the distance of sampling sites from the sea and thus the extent of sea spray impact. This study covers measurements of rainfall (P) and air temperature (T), physicochemical parameters (pH, specific electrolytic conductivity (SEC), major ions (Cl , NO3 , SO4...
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Release of selected chemical elements from shale drill cuttings to aqueous solutions of different pH
PublicationThe effect of pH changes on leachability of light and heavy metals from shale drill cuttings generated from unconventional shale gas production was investigated. Cuttings, being the primary byproduct generated from drilling operations, belong to the potentially hazardous type of wastes due to presence of heavy and radioactive elements and remains of drilling fluid. In this regard, assessment of potentially dangerous components...
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Processing and properties of Al-Si-Fe-Cr in situ composites
PublicationPraca jest kontynuacją badań nad wytwarzaniem tanich kompozytów in situ o osnowie stopu Al-Si wzmocnionego związkami międzymetalicznymi Al-Fe-Si lub Al-Fe-Cr-Si, otrzymanych poprzez reakcję ciekłego stopu Al (Al-Si11, Al-Si25) z proszkiem Fe lub Cr. Żelazo zostało wybrane ze względu na niską cenę, niską temperaturę wytwarzania, wysoką reaktywność z Al i heksagonalną sieć krystalograficzną związku Al-Fe-Si, co sprzyja tworzeniu...
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Effect of Cr and Mn doping on ferroelectric and dielectric properties of Li1.72Na0.28Ge4O9 single crystals
PublicationLi1.72Na0.28Ge4O9 single crystals pure and slightly doped with chromium and manganese, obtained by Czochralski growth, were investigated for their ferroelectric and dielectric properties. The change in stoichometry of Li2− x Na x Ge4O9 (x = 0.28) crystals doped with Cr and Mn (0.1 mol.%) had an influence on the value of ferroelectric-to-paraelectric phase transition temperature, T c. The applied doping affects the T c value by...
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Influence of laser beam machining on the cavitation resistance of Fe-Cr-Co clad.
PublicationW pracy przedstawiono wpływ laserowego nagrzewania bezzmiany stanu skupienia i laserowego przetapiania napoin ze stopu Fe-Cr-Co na ich odporność kawitacyjną. Badania kawitacyjne prowadzono na stanowisku z wirującą tarczą. Plastyczne odkształcenia powierzchni określano za pomocą analizy obrazów erodowanych powierzchni. Uzyskane rezultaty wskazują, że laserowo obrabiane powierzchnie miały różną podatność do plastycznego odkształcania...
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Microstructure and Electrical Properties of Fe,Cu Substituted (Co,Mn)3O4 Thin Films
PublicationIn this work, thin films (~1000 nm) of a pure MnCo2O4 spinel together with its partially substituted derivatives (MnCo1.6Cu0.2Fe0.2O4, MnCo1.6Cu0.4O4, MnCo1.6Fe0.4O4) were prepared by spray pyrolysis and were evaluated for electrical conductivity. Doping by Cu increases the electrical conductivity, whereas doping by Fe decreases the conductivity. For Cu containing samples, rapid grain growth occurs and these samples develop cracks...
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Determination of the Major By-Products of Citrus hystrix Peel and Their Characteristics in the Context of Utilization in the Industry
PublicationKaffir lime (Citrus hystrix) is a popular citrus in Southeast Asia. Despite the growing interest in the peel of the fruit, the leaves are the most frequently used part of the fruit. The aim of the study was to determine the main by-products of the peel, such as pectins, minerals, essential oil, and bioactive compounds, and to evaluate the possibility of using them in various branches of industry. In the study of the essential oil...
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Susceptibility of Cr-Ni-Mn steel to the hydrogen degradation in boiler fuel = Podatnośc stali Cr-Mn-Ni na niszczenie wodorowe w paliwie kotłowym
PublicationStal 34HNM poddana różnym obróbkom cieplnym wykazała skłonność do korozji naprężeniowej w pomiarach ze stałą niską szybkością rozciągania i do zmęczenia korozyjnego niskocyklowego. Mechanizmem zniszczenia była degradacja wodorowa. Możliwe źródła pochłaniania wodoru to: korozja, degradacja węglowodorów z tworzeniem się kwasów organicznych i promotorów wnikania wodoru.
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3 d 3 system – Comparison of Mn 4+ and Cr 3+ in different lattices
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The accumulation of metal (Co, Cr, Cu, Mn and Zn) in freshwater Ulva (Chlorophyta) and its habitat
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Bioaccessibility of Ca, Cu, Fe, Mg, Mn and Zn from commercial bee honeys
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The XRD diffraction patterns of (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials after reduction at 900 deg.C in hydrogen
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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The XRD diffraction patterns of (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials after reduction at 1000 deg.C in hydrogen
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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The XRD diffraction patterns of (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials after reduction at 1100 deg.C in hydrogen
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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The XRD diffraction patterns of as-prepared (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials synthesized via the solid state reaction method
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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Morphology changes in Fe-Cr porous alloys upon high-temperature oxidation quantified by X-ray tomographic microscopy
PublicationThe effect of high-temperature oxidation at 850 C (10 h, 30 h, 100 h) and 900 C (10 h) on porous (30 % porosity) ferritic stainless steel (Fe22Cr) has been investigated using synchrotron tomographic microscopy, which allowed for visualisation, separation and quantitative analysis of the metallic core, closed pores, open pores and oxide scale phase. The same regions within the samples were investigated before and after oxidation...
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New Green Determination of Cu, Fe, Mn, and Zn in Beetroot Juices along with Their Chemical Fractionation by Solid-Phase Extraction
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Physicochemical properties of rock salt-type ordered Sr2MMoO6 (M=Mg, Mn, Fe, Co, Ni) double perovskites
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Synthesis, structure and physical properties of Ru ferrites: BaMRu5O11 (M=Li and Cu) and BaM′2Ru4O11 (M′=Mn, Fe and Co)
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Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnects
PublicationThe “in-situ” Fe-doping of the manganese cobalt spinel was achieved by electrophoretic co-deposition of Mn1,5Co1,5O4 and Fe2O3 powders followed by a two-step reactive sintering treatment. The effects on the coating properties of two different Fe-doping levels (5 and 10 wt.% respectively) and two different temperatures of the reducing treatment (900 and 1000 °C) are discussed. Samples with Fe-doped coatings demonstrated a lower...
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A- and B-site doping effect on physicochemical properties of Sr2−xBaxMMoO6 (M = Mg, Mn, Fe) double perovskites — candidate anode materials for SOFCs
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Influence of Cd(II), Cr(VI) and Fe(III) on early steps of deetiolation process in wheat: fluorescence spectral changes of protochlorophyllide and newly formed chlorophyllide
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A heterotrimetallic synthetic approach in versatile functionalization of nanosized {MxCu13–xW7}3+ and {M1Cu8W6} (M = Co, Ni, Mn, Fe) metal–cyanide magnetic clusters
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High temperature corrosion resistance of porous hastelloy alloy
PublicationTo further understand the suitability of Ni-Cr-base alloy for solid oxide fuel cell (SOFC), a commercial Ni-Cr-Fe-Mo alloy, Hastelloy X was selected and evaluated for oxidation behaviour under high temperature conditions. HastelloyX was chosen due to its unusual resistance to oxidizing, reducing and neutral atmospheres. For long term stability of metal supported fuel cell, the corrosion resistance plays a vital role and must be...
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Jan Michalski dr hab. inż.
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Development and optimization of simplified method of fast sequential HR-CS-FAAS analysis of apple juices on the content of Ca, Fe, K, Mg, Mn and Na with the aid of response surface methodology
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HR-CS FAAS based method for direct determination of total concentrations of Ca, Fe, Mg and Mn in functional apple beverages and evaluation of contributions of the bioaccessible fraction of these elements by in vitro gastrointestinal digestion and chemical fractionation
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Room temperature solvent extraction for simple and fast determination of total concentration of Ca, Cu, Fe, Mg, Mn, and Zn in bee pollen by FAAS along with assessment of the bioaccessible fraction of these elements using in vitro gastrointestinal digestion
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Odporność kawitacyjna struktury austenitycznej otrzymywanej metodami obróbki laserowej
PublicationPrzedstawiono badania odporności kawitacyjnej struktur austenitycznych otrzymanych poprzez obróbkę laserową stali 1H18N9 i 45. Stal 1H18N9 stopowano Mn i TiC natomiast warstwę wierzchnią stali 45 stopowano Ni, Mn, Cr i Nb.
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SEM examination of surface layer of C45 steel after grinding on defferent depth
Open Research DataFerrite examination for the medium carbon structural steel with low content of Mn, Si, Cu, Cr and Ni after its grinding to a depth of 2 µm, 8 µm, 14 µm and 20 µm, at constant wheel circumferential speed of vs = 25 m/s and constant feed rate vft = 1 m/min. It was shown that the grinding of C45 steel causes strong work hardening of ferrite in surface...
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Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterization
PublicationWe report a systematic microstructural and electrical characterization of iron doped Mn–Co spinel coatings processed by electrophoretic co-deposition of Mn1.5Co1.5O4 and Fe2O3 powders on Crofer 22 APU and AISI 441 steel substrates. Iron addition to Mn–Co spinel coating leads to a reduction of the area specific resistance on both substrates, after 3200 h at 750 °C. The Fe doped Mn–Co coating both leads to a thinner oxide scale and...
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Odporność kawitacyjna laserowo kształtowanych struktur na stali 45
PublicationPrzedstawiono badania odporności kawitacyjnej różnych struktur otrzymanych na stali 45 po laserowym stopowaniu jej powierzchni proszkami Ni, Mn. Cr, Nb, Mo, Ti, Co.
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Electrophoretic co-deposition of Mn1.5Co1.5O4, Fe2O3 and CuO: Unravelling the effect of simultaneous addition of Cu and Fe on the microstructural, thermo-mechanical and corrosion properties of in-situ modified spinel coatings for solid oxide cell interconnects
PublicationA systematic microstructural, thermo-mechanical and electrical characterization of simultaneous Fe–Cu doped Mn–Co spinel coatings processed by electrophoretic co-deposition on Crofer 22 APU is here reported and discussed. An innovative approach for the simultaneous electrophoretic deposition of three spinel precursors is designed, conceived and optimised, with the aim of outlining time- and energy-saving spinel modification routes....
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The XAS spectra of O-K edges, M-L edges and Ce-M edges in Ce0.9M0.1O2
Open Research DataThe dataset consists of XAS spectra of O-K edges, M-L edges of Ce0.9M0.1O2 (where M=Mn, Fe, Co, Ni, Cu) synthesised by reverse microemulsion method. XAS spectra were collected at PIRX beamline in SOLARIS National Synchrotron Radiation Centre. Measurements were perfomed under ultra high vacuum in total electron yield (TEY) mode.
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The TPR reduction profile of Ce0.9M0.1O2
Open Research DataThe dataset includes the TPR reduction profiles of Ce0.9M0.1O2 (where M=Mn, Fe, Co, Ni, Cu) nanopowders prepared by the reverse microemulsion method. After the synthesis powders were dried, then calcined at 500 degrees for 2 h. The measurements were carried out in H2/Ar mixture from 100C to 900C. Gas flow:40ml/min and temperature ramp: 10deg/min.
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Manganese–Cobalt Based Spinel Coatings Processed by Electrophoretic Deposition Method: The Influence of Sintering on Degradation Issues of Solid Oxide Cell Oxygen Electrodes at 750 °C
PublicationThis paper seeks to examine how the Mn–Co spinel interconnect coating microstructure can influence Cr contamination in an oxygen electrode of intermediate temperature solid oxide cells, at an operating temperature of 750 °C. A Mn–Co spinel coating is processed on Crofer 22 APU substrates by electrophoretic deposition, and subsequently sintered, following both the one-step and two-step sintering, in order to obtain significantly...
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The XRD diffraction patterns of Ce0.9M0.1O2 prepared using the reverse microemulsion method
Open Research DataThe dataset includes XRD patterns of Ce0.9M0.1O2 (where M=Mn, Fe, Co, Ni, Cu) nanopowders prepared using the reverse microemulsion method. The powders were precipitated from organic-based solution using tetramethylammonium hydroxide (TMAOH). After the precipitation, the sediment was centrifuged and rinsed with alcohol several times. Precursors powder...
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Laserowe stopowanie technicznego żelaza w celu zwiększenia jego odporności kawitacyjnej
Publicationprzedstawiono wyniki badań odporności kawitacyjnej technicznego żelaza po laserowym stopowaniu jego powierzchni proszkami Mn, Ti, Cr, Si. Obróbka laserowa spowodowała 6-krotny wzrost twardości i wzrost odporności na odkształcenia plastyczne spowodowane działaniem obciążeń kawitacyjnych.
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Some coatings of high cavitation resistance produced by CO2 laser beam. XIV International Symposium on Gas Flow, Chemical Lasers and High Power Lasers.
PublicationPrzedstawiono wyniki badań odporności kawitacyjnej stali 2H13, 45 i żelaza Armco po laserowym stopowaniu ich powierzchni różnymi kompozycjami proszków Co, Mo, Ni, Mn i Cr, Ti. Wykazano różne własności kawitacyjne otrzymanych warstw w zależności od otrzymanej mikrostruktury.
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Spatial and vertical distribution analysis of heavy metals in urban retention tanks sediments: a case study of Strzyza Stream
PublicationConcentrations of seven heavy metals (HMs): Zn, Cu, Pb, Cd, Ni, Cr, and Fe in core samples of bottom sediments from four retention tanks (RTs) located along the Strzyza Stream in northern Poland (Gdansk) were measured to obtain a general view of sediment quality. The recognition of contamination and potential environmental impacts is the main aim of this paper. A total of 96 sediment samples were collected from eight sampling sites...
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Relationship between microstructure of laser alloyed of C45 steel and its cavitation resistance.
PublicationPrzedstawiono badania odporności kawitacyjnej stali C45 po laserowym stopowaniu jej powierzchni proszkami Mn., Ni, Cr, Nb, Mo, Co. Stwierdzono, że warstwa wierzchnia posiada wyższą odporność kawitacyjną jeśli w jej mikrostrukturze występuje pewna ilość austenitu zwiększająca podatność do wzmacniania odkształceniowego.
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The 3d Ce XPS spectra of Ce0.9M0.1O2
Open Research DataThe dataset consists of 3d Ce XPS of Ce0.9M0.1O2 where (M=Mn, Fe, Co, Ni, Cu). X-ray Photoelectron Spectroscopy analysis (XPS) was performed using X-ray photoelectron spectrometer Omnicron NanoTechnology with 128-channel collector. XPS measurements were undertaken in ultra-high vacuum conditions, below 1.1x10-8 mbar. Photoelectrons were excited by an...
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The XRD diffraction patterns of annealed Ce0.9M0.1O2 powders prepared using the reverse microemulsion method
Open Research DataThe dataset includes XRD patterns of Ce0.9M0.1O2 (where M=Mn, Fe, Co, Ni, Cu) nanopowders prepared using the reverse microemulsion method. The powders were precipitated from organic-based solution of nitrates using TMAOH. The sediment was cetrifuged and rinsed with alcohol several times. Powders were dried and calcinated at 500 degrees for 2 h, followed...
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The 2p XPS spectra of transition metals in Ce0.9M0.1O2
Open Research DataThe dataset consists of 2p XPS spectra of transition metals in Ce0.9M0.1O2 where (M=Mn, Fe, Co, Ni, Cu). X-ray Photoelectron Spectroscopy analysis (XPS) was performed using X-ray photoelectron spectrometer Omnicron NanoTechnology with 128-channel collector. XPS measurements were undertaken in ultra-high vacuum conditions, below 1.1x10-8 mbar. Photoelectrons...
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The fate and contamination of trace metals in soils exposed to a railroad used by Diesel Multiple Units: Assessment of the railroad contribution with multi-tool source tracking
PublicationSoil samples from cut slopes from lightly loaded railway lines used by Diesel Multiple Units for 5 years in Gdansk (Poland) were collected and analyzed for trace metals (TMs): Zn, Pb, Cd, Ni, Cr, Cu, and Fe. The main aim was to assess soil enrichment, contamination status, and distribution of TMs relative to the distance from the railway track. Extensive source tracking analyses were performed using cluster analysis (CA) and the...
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Cavitation erosion of some laser-produced iron-base corrosion-resistance alloys
PublicationW pracy przedstawiono badania kawitacyjne stali C45, X20Cr13 oraz X5CrNi18-10 po laserowym stopowaniu ich warstwy wierzchniej proszkami Mn, Cr, Ni, Si, Ti, Co, Al, Mo, B. Badania kawitacyjne prowadzono na stanowisku z wirującą tarczą. Zniszczenia powierzchni w okresie inkubacji oceniano metodą optyczną. Przedstawiono związek pomiędzy uzyskaną mikrostrukturą obrabianej warstwy i jej odpornością kawitacyjną.
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High temperature oxidation behavior of SUS430 SOFC interconnects with Mn-Co spinel coating in air
PublicationIn this study, SUS430 alloy is evaluated for its high temperature corrosion properties as a possible material for interconnects of solid oxide fuel cells (SOFCs). Samples are coated with Mn-Co by commercial physical vapor deposition (PVD) process and oxidized in air for 1250 h at 800 °C. A dense cubic Mn-Co-Fe spinel layer is formed on the surface, showing great effect on corrosion reduction compared with the samples without coating....
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Speciation of heavy metals in bottom sediments of drinking water reservoir for Gdansk, Poland – changes over the 14 years
PublicationThere was conducted a comparative study of the concentrations of heavy metals (Zn, Cu, Pb, and Cd) in the surface layer of sediments collected in two investigation periods: 1999–2000 and 2013. Theresults demonstrated that the degree of metals pollution decreased over time. The contamina-tion factors (Cf) calculated for Zn, Cu, Pb, and Cd were respectively 3.63, 3.86, 3.23, and 3.25 in the first period of research and 1.35, 3.42,...
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Speciation of heavy metals in bottom sediments of a drinking water reservoir for Gdańsk, Poland – changes over the 14 years
PublicationThere was conducted a comparative study of the concentrations of heavy metals (Zn, Cu, Pb, andCd) in the surface layer of sediments collected in two investigation periods: 1999–2000 and 2013.The results demonstrated that the degree of metals pollution decreased over time. The contaminationfactors (Cf) calculated for Zn, Cu, Pb, and Cd were respectively 3.63, 3.86, 3.23, and 3.25 in thefirst period of...
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Dissimilar autogenous TIG joint of Alloy 617 and AISI 304H steel for AUSC application
PublicationTo reduce costs and improve high-temperature performance in Advanced Ultra Super Critical (AUSC) boilers, it is necessary to weld austenitic steel to Inconel alloy. In this study, the autogenous tungsten inert gas (TIG) welding process was used to join Alloy 617 and an austenitic AISI 304H steel plate of thickness 5 mm. Microstructural analysis showed that the microstructure formation was uneven along the weldments, with columnar...
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Cavitation Erosion Resistance of Austenitic Microstructure Created byLaser Beam
PublicationPraca przedstawia własności kawitacyjne różnych mikfrostruktur austenitycznych tworzonych za pomocą wiązki lasera na stalach X5CrNi18-10 oraz C45. Stal X5CrNi18-10 była laserowo stopowana węglikiem TiC oraz stopowana Ni, Mn, Cr i Nb. Jako żródło mocy stosowany był laser CO2. Własności kawitacyjne oceniane były na stanowisku z wirującą tarczą. Badania ujawniły różną podatność struktury austenicycznej do odkształceń plastycznych...
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Phosphorus concentration and availability in raw organic waste and post fermentation products
PublicationThe aim of the study was to determine the mobility of phosphorus forms in raw organic waste and from the solid and liquid fractions of digestate. To achieve the purpose of this study, the components (including livestock manure, agricultural waste, food waste, sewage sludge) and their post fermentation products were considered. Subsequently, the effect of the fermentation process on the mobility of phosphorus forms in post-fermentation fractions...
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Design and Preparation of Magnetically-Oriented Poly(styr-co-MMA)-3MPS Capped Fe(ZnO) Hybrid Microspheres for Ion Exchange Removal of Toxic Pollutants from Wastewater
PublicationIn this work, polymeric microspheres derived from polystyrene-co-methyl methacrylate embedded with magnetic ZnO nanoparticles (poly(styrene-co-MMA)-3MPS-Fe (ZnO)) were synthesized using the suspension polymerization method. The surfaces of polymeric Fe(ZnO) microspheres were improved by functionalization with amino and sulphonate groups. The physicochemical analysis indicated a large number of positively charged (anion exchange)...
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Effect of interconnect coating procedure on solid oxide fuel cell performance
PublicationChromium (Cr) species vaporizing from chromia-forming alloy interconnects is known as a source of degradation in solid oxide fuel cell (SOFC) stacks called “cathode poisoning”. (Mn,Co)3O4 spinel coatings offer good protection against Cr evaporation during operation. In this study, Crofer 22 APU steel interconnects were electrophoretically deposited in different mediums to obtain high packing of green coating layer. The optimized...
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Comparison of Cu1.3Mn1.7O4 spinels doped with Ni or Fe and synthesized via wet chemistry and solid-state reaction methods, designed as potential coating materials for metallic interconnects
PublicationThe influence of the method applied to synthesize Cu-Mn-O spinel was evaluated. The methods selected for the investigation were EDTA gel processes and solid-state reaction synthesis. From the obtained powders, sinters were prepared and assessed in terms of their properties as potential coating materials. Additionally, the influence of Ni and Fe dopants was evaluated. The results show that the EDTA gel processes method seems to...
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Usuwanie arsenu z wody podziemnej w procesie zintegrowanym - koagulacja/mikrofiltracja
PublicationW pracy przedstawiono wyniki badań przeprowadzonych w skali ułamkowo technicznej nad zastosowaniem procesu koagulacji (współwytrącania) jonami żelaza, zintegrowanego z mikrofiltracją, do usuwania arsenu z wody podziemnej, zawierającej ok. 40 μg As/l, 0,70 mg Fe/l oraz 0,09 mg Mn/l. Jako koagulant zastosowano wodny roztwór siarczanu żelaza (III), w dawkach od 0,5 do 18 mg Fe/l. W badaniach wykorzystano rurowe membrany mikrofiltracyjne...
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Diamond-Based Supercapacitors with Ultrahigh Cyclic Stability Through Dual-Phase MnO2-Graphitic Transformation Induced by High-Dose Mn-Ion Implantation
PublicationWhile occasionally being able to charge and dischargemore quickly than batteries, carbon-based electrochemical supercapacitors(SCs) are nevertheless limited by their simplicity of processing, adjustableporosity, and lack of electrocatalytic active sites for a range of redox reactions.Even SCs based on the most stable form of carbon (sp3carbon/diamond)have a poor energy density and inadequate capacitance retention during longcharge/discharge...
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The role of atmospheric precipitation in introducing contaminants to the surface waters of the Fuglebekken catchment, Spitsbergen.
PublicationAlthough the Svalbard Archipelago is located at a high latitude, far from potential contaminant sources, it is not free from anthropogenic impact. Towards the Fuglebekken catchment, in the southern part of Spitsbergen, north of Hornsund fjord, contaminants can be transported from mainland pollution sources. In the precipitation and surface water collected in the catchment, the following elements were detected and quantified: Ag,...
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The effects of urban vehicle traffic on heavy metal contamination in road sweeping waste and bottom sediments of retention tanks
PublicationDiffuse pollution formed during a surface runoff on paved surfaces is a source of heavy metals (HMs) of various origin. This research study indicates the connection between bottom sediments of retention tanks located on urban streams and road sweeping wastes (RSW) that migrate during surface runoff to the stormwater drainage systems with discharge to the retention tanks. Moreover, we test the primary sources of HMs in RSW by analysing...
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Formation enthalpies of LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) interlanthanide perovskites
PublicationHigh-temperature oxide melt solution calorimetry using 3Na2O·MoO3 at 802 °C was performed for interlanthanide perovskites LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) and lanthanide oxides (La2O3, Ho2O3, Er2O3, Tm2O3 and Yb2O3). The enthalpies of formation of these interlanthanide perovskites from binary lanthanide oxides at room temperature (25 °C) were determined to be −8.3±3.4 kJ/mol for LaHoO3, −9.9±3.0 kJ/mol for LaErO3, −10.8±2.7 kJ/mol...
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Chemometric Evaluation of WWTPs’ Wastewaters and Receiving Surface Waters in Bulgaria
PublicationWastewater treatment plant (WWTP) installations are designed and operated to reduce the quantity of pollutants emitted to surface waters receiving treated wastewaters. In this work, we used classical instrumental studies (to determine chemicals and parameters under obligations put with Directive 91/271/EEC), ecotoxicological tools (Sinapis alba root growth inhibition (SA-RG) and Heterocypris incongruens mortality (MORT) and growth...
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Fe-modified Mn2CuO4 spinel oxides: coatings based on abundant elements for solid oxide cell interconnects
PublicationThe current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition,...
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Multilayer coatings based on cerium oxide and manganese cobaltite spinel for Crofer22APU SOC interconnects
PublicationThe current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition,...
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Study on Microstructure-Property Relationship of Inconel 617 Alloy/304L SS Steel Dissimilar Welds Joint
PublicationWelding of Inconel 617 (IN617) alloy and austenitic 304L SS steel has been attempted using the autogenous Laser Beam Welding (LBW) process. Characterization of dissimilar weldments was performed on either side of the fusion boundaries. The metallographic results showed that the inhomogeneous microstructure formation for weld metal contained columnar and cellular dendrites near the interface, whilst the columnar, cellular and equiaxed...
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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublicationThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Reemission of inorganic pollution from permafrost? A freshwater hydrochemistry study in the lower Kolyma basin (North-East Siberia)
PublicationPermafrost regions are under particular pressure from climate change resulting in widespread landscape changes, which impact also freshwater chemistry. We investi- gated a snapshot of hydrochemistry in various freshwater environments in the lower Kolyma river basin (North-East Siberia, continuous permafrost zone) to explore the mobility of metals, metalloids and non-metals resulting from permafrost thaw. Partic- ular attention...
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Analiza osadów dennych pod kątem ich właściwości nawozowych
PublicationThe analysis of bottom sediments in terms of their fertilizing properties. In paper the characterize of sediments as product to nature usage was done. Analyzed material was taken from ecological treatment system located in wastewater treatment plant in Swarzewo (Pomerania Region) about flow Q= 6000 m3/d. Measurements of dry matter and organic matter content, as well as nitrogen concentrations and phosphorus fractions: loosely...
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Partitioning of heavy metals in sub-surface flow treatment wetlands receiving high-strength wastewater
PublicationThe retention of heavy metals at two pilot-scale treatment wetlands (TWs), consisting of two vertical flow beds (VSSF) followed by a horizontal flow bed (HSSF) was studied. The TWs received highstrength wastewater: reject waters from sewage sludge centrifugation (RW) and landfill leachate (LL). The concentrations of metals: Fe, Mn, Zn, Al, Pb, Cu, Cd, Co, Ni were measured in treated wastewater, substrate of the beds and in plant...
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Surface sediments pollution due to shipwreck s/s “Stuttgart”: a multidisciplinary approach
PublicationShipwrecks may pose a serious source of pollution for marine ecosystems. For this reason, it is of great importance to perform a marine ecosystem risk assessment due to plausible wreck presence. One of elements of such an assessment is determining the state of the environment in the vicinity of the wreck. In the work presented, the results of studies on surface sediments samples collected around the s/s Stuttgart ship sunk during...
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Seasonal and spatial differences in metal and metalloid concentrations in the snow cover of Hansbreen, Svalbard
PublicationMetals and metalloids in snow on glaciers, depending on the season of deposition, may come from various sources: local rock dust (erosion of the geological substratum), marine aerosol, local human activity (e.g. fuel combustion, waste incineration) and long-range atmospheric transport. Hansbreen glacier, located close to the Polish Polar Station in Svalbard, is a perfect site to study metals and metalloids: it has complex geological...
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In-situ Cu-doped MnCo-spinel coatings for solid oxide cell interconnects processed by electrophoretic deposition
PublicationThe Cu doping of the Mn–Co spinel is obtained “in-situ” by electrophoretic co-deposition of CuO and Mn1.5Co1.5O4 powders and subsequent two-step reactive sintering. Cu-doped Mn1.5Co1.5O4 coatings on Crofer22APU processed by electrophoretic co-deposition method are tested in terms of long term oxidation resistance and area specific resistance tests up to 3600 h. The introduction of Cu in the spinel lead to higher level of densification...
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Chiral Schiff base complexes as an effective catalyst in Diels-Alder reaction
PublicationDiels Alder reaction is a very important tool in carbon-carbon bond formation. It is a cycloaddition between a conjugated diene and a second compound called dienophile. Where one or more heteroatoms are present in the diene and/or dienophile framework, the cycloaddition is called hetero-Diels-Alder reaction (HDA). The asymmetric Diels-Alder reaction is among the most powerful available methodologies for that construction of optically...
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INFLUENCE OF CERAMIC COATING ON MECHANICAL PROPERTIES OF STAINLESS STEEL
PublicationCrystal structure and phase composition of stainless steel substrates (AISI 304 type) was studied and it was found that they adopted the cubic symmetry. The calculated elementary cell parameter for the mayor Fe-Ni phase (weight fraction 99%) was a = 3.593 Å, whereas the mean grain size was = 2932 Å. Morphology of the stainless steel substrate surface was studied with profilometry. Mechanical properties of the stainless steel...