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Hybrid battery based on arylated carbon nanotubes and laccase
PublicationSingle-walled carbon nanotubes (SWCNT) were covalently modified with anthracene and anthraquinone and used for the construction of cathodes for biocatalytic reduction of dioxygen. The nanotubes with aromatic groups casted onto the electrode increased the working surface of the electrode and enabled efficient direct electron transfer (DET) between the enzyme and the electrode. The aryl groups enter the hydrophobic pocket of the...
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Structure of EstA esterase from psychrotrophic Pseudoalteromonas sp. 643A covalently inhibited by monoethylphosphonate.
PublicationThe crystal structure of the esterase EstA from the cold-adapted bacteriumPseudoalteromonas sp. 643A was determined in a covalently inhibited form at aresolution of 1.35 A˚. The enzyme has a typical SGNH hydrolase structureconsisting of a single domain containing a five-stranded beta-sheet, with threehelices at the convex side and two helices at the concave side of the sheet, and isornamented with a couple of very short helices...
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Engendering responsibility in architecture students through real planning for a tram depot in Gdańsk
PublicationApart from technical competencies, the profession of architect requires specific social competencies: understanding the user’s needs, ability to diagnose social problems, negotiating and understanding the impact of construction investments on society and the environment. The architect plays a significant role in the collective effort to create spatial order. This is why it is important to include these social competencies in the...
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Synthesis, Antimicrobial and Mutagenic Activity of a New Class of d-Xylopyranosides
PublicationEight N-[2-(2′,3′,4′-tri-O-acetyl-α/β-d-xylopyranosyloxy)ethyl]ammonium bromides, a new class of d-xylopyranosides containing a quaternary ammonium aglycone, were obtained. Their complete structure was confirmed using NMR spectroscopy (1H, 13C, COSY and HSQC) and high-resolution mass spectrometry (HRMS). An antimicrobial activity against fungi (Candida albicans, Candida glabrata) and bacteria (Staphylococcus aureus, Escherichia...
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Water uptake and energetics of the formation of barium zirconate based multicomponent oxides
PublicationA group of multi-component oxides based on BaZrO3 have been prepared using a solid-state reaction method and examined in terms of their water uptake and thermodynamics of formation. Depending on the type and amount of acceptor substitution, the synthesized compounds exhibit various proton defect concentrations, reaching up to 0.2 mol/mol for a compound containing 10 different elements in the B-sublattice, where 50% of them are...
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Drug-Eluting Biopsy Needle as a Novel Strategy for Antimicrobial Prophylaxis in Transrectal Prostate Biopsy
PublicationOBJECTIVES: To preclinically evaluate drug-eluting biopsy needles (patent pending WO2016118026) as a new potential way of antimicrobial prophylaxis for transrectal prostate biopsy. METHODS: Twenty steel biopsy needles have been coated with polyvinyl alcohol, ciprofloxacin, and amikacin. Modified biopsy needles have been randomly divided into 3 groups (1:2:1 ratio). Needles from group I were immersed for 30 minutes in dedicated...
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Effect of pH on optical sensing with poly-L-lysine-modified nanodiamonds
PublicationNitrogen-vacancy (NV) centers are crystallographic defects which provide diamonds with unique physical properties. The centers are known for their intensive, time-stable fluorescence, and an electron spin, which exhibits long coherence time and may be manipulated using external stimuli. Nanodiamonds containing the NV centers are promising tools in biolabeling, biosensing, and drug delivery due to the aforementioned properties of...
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Shooting Gas Cylinders to Prevent Their Explosion in Fire
PublicationGas cylinders in general, and particularly cylinders containing acetylene, constitute a great potential danger to fire and rescue services involved in salvage operations. Experiments show that gas cylinders with acetylene, oxygen, hydrogen, CNG, LPG or CO2 may blow after short exposition to heat with very destructive effect as fragments of blown cylinder may fly even several hundred meters. In the case of acetylene the explosion...
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Reaktory elektrochemiczne w przemyśle - konstrukcja i zastosowania
PublicationZ biegiem lat reakcje elektrochemiczne przestały być postrzegane jedynie jako eksperymenty laboratoryjne lub proste baterie. Chociaż mechanizm reakcji i budowa prostych reaktorów znana jest ludzkości już od ponad 100 lat w ostatnich latach można zauważyć największy wzrost zainteresowania tą dziedziną. Nowy stale opracowywane są lepsze projekty budowy reaktorów. Modyfikacje to nie tylko rodzaje i formy materiałów, z których wykonane...
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Fabrication and properties of electrode material composed of ordered titania nanotubes and pEDOT:PSS
PublicationWe report on the two-stage preparation method of electrode material composed of titania nanotubes and poly(3,4-ethylenedioxythiopene):poly(2-styrenesulphonate) conductive polymer (pEDOT:PSS). Initially, titania nanotube arrays were produced by the anodization process of Ti substrate. Next, the polymer was potentiostatically deposited onto the thermally annealed nanotube arrays from the electrolyte containing monomer and counter...
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Development of novel smartphone-based methods of wine quality assessment
PublicationThe doctoral dissertation concerns the development of novel smartphone-based analytical methods of wine quality evaluation, which would be in line with the stipulations of green and equitable analytical chemistry. This solution is based on the analysis of biogenic amines and selected bioactive compounds. The dissertation is based on four articles containing the results of research which led to the development of smartphone-based...
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The possibility of the application of a potentiometric sensor with all-solid-state electrodes for the quality control of different natural waters
PublicationThe quality of various natural waters was examined by a new potentiometric sensor with six all solid state electrodes containing an appropriate lipophilic compound in a polymer membrane. Physicochemical parameters such as conductivity and acidity of tested waters were also tested. All waters were neutral or slightly alkaline and contained different ions (e.g., Cl–) due to the place of their sampling (a coastal zone and a moraine...
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Positron collisions with molecular hydrogen: cross sections and annihilation parameters calculated using theR-matrix with pseudo-states method
PublicationThe molecular R-matrix with pseudo-states (MRMPS) method is employed to study positron collisions with H2. The calculations employ pseudo-continuum orbital sets containing up to h (l = 5) functions. Use of these high l functions is found to give converged eigenphase sums. Below the positronium formation threshold, the calculated cross sections agree with other high-accuracy theories and generally with the measurements. Calculation...
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Capacitance Enhancement by Incorporation of Functionalised Carbon Nanotubes into Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Composites
PublicationThis paper reports on the role of oxidised carbon nanotubes (oxMWCNTs) present in poly-3,4-ethylenedioxytiophene (PEDOT)/graphene oxide (GOx) composite. The final ternary composites (pEDOT/GOx/oxMWCNTs) are synthesised by an electrodeposition process from the suspension-containing monomer, oxidised carbon nanotubes and graphene oxide. Dissociated functional groups on the surface of graphene oxide play a role of counter-ions for the...
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Corrosion Inhibition of Aluminium Alloy AA6063-T5 by Vanadates: Local Surface Chemical Events Elucidated by Confocal Raman Micro-Spectroscopy
PublicationChemical interactions between aqueous vanadium species and aluminium alloy AA6063-T5 were investigated in vanadate-containing NaCl solutions. Confocal Raman and X-ray photoelectron spectroscopy experiments were utilised to gain insight into the mechanism of corrosion inhibition by vanadates. A greenish-grey coloured surface layer, consisting of V+4 and V+5 polymerized species, was seen to form on the alloy surface, especially on...
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Small Urban Hacks - Big Impact! Tackling major urban challenges through acupunctural smallness
PublicationSmall urban hacks, acupunctural action and process-oriented planning approaches might appear to address quite a socio-romantic attitude towards our urban environments. In this chapter, our aim is to remedy such a biased view, demonstrating the impact and potential of smallness in the context of major urban challenges. Small urban hacks and their multi-faceted and creativity-driven approaches of small is beautiful are selected from...
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Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film
PublicationIn this work the effects of electropolymerization conditions on the morphological properties and conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) film have been studied. PEDOT films were electrochemically synthesized in a one step process from acetonitrile solution containing 3,4-ethylenedioxythiophene (EDOT) and lithium perchlorate. Based on atomic force microscopy, scanning electron microscopy, cyclic voltammetry and...
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Luminescence properties of Eu3+ and Tb3+ doped silica-based xerogels
PublicationPure SiO2 xerogels and SiO2 xerogels containing SrF2: Eu3+/: Tb3+ crystals were prepared using sol-gel method. Luminescent spectra showed excitation and emission peaks characteristic to Eu3+ and Tb3+ 4f - 4f transitions. ET Tb3+→Eu3+ has been observed. XRD pattern of SiO2 matrix confirmed lack of long range order. Patterns of SiO2-SrF2:Eu3+ and SiO2-SrF2:Tb3+ showed peaks corresponding to SrF2. SEM images have shown agglomerates...
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Chemical structure, thermal and mechanical characterization of bio-based polyurethane composites filled with microcrystalline cellulose
PublicationOver the past several decades, the interest in replacing the synthetic components used in the production of polymers and composites with their natural counteparts has been growing. Biocomposites belong to the group of materials produced with the use of renewable raw materials. There has been a recent surge of interest in the industrial applications of composites containing natural fibres reinforced with biopolymers. Biopolymers...
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Determination of 3,4-methylenedioxy-α-pyrrolidinobutiophenone (MDPB) in blood. A case report
PublicationSynthetic drugs, known as ‘‘legal highs’’, are still very popular on black market. The determination of their composition are required in courts of law and also to understand what potential users may be subjected to. The interest of new cathinones, e.g. MDPBP, is in view of psychoactive effects that they cause and that, in many cases, they are not controlled by law. The case outlined here concerns 19 years-old man, who was found...
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Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide
PublicationMicroporous polyurethanes (MPU) were modified by adding 0.25%–1.25 wt% of reduced graphene oxide (RGO). The materials were prepared without solvent via in situ polymerization. From a technological point of view, it is very important to obtain functional materials by using reacting compounds only. The thermal characteristics of obtained MPU were investigated using TGA, DSC, and DMA techniques. In comparison to nonmodified microporous...
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Efficient analysis of structures with rotatable elements using model order reduction
PublicationThis paper presents a novel full-wave technique which allows for a fast 3D finite element analysis of waveguide structures containing rotatable tuning elements of arbitrary shapes. Rotation of these elements changes the resonant frequencies of the structure, which can be used in the tuning process to obtain the S-characteristics desired for the device. For fast commutations of the response as the tuning elements are rotated, the...
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Determination of Biogenic Amines in Wine Using Micellar Electrokinetic Chromatography
PublicationProduction on a large-scale of fermented alcoholic drinks made from different kinds of fruits is carried out in homes. Although wine laws regulating home production exist, they do not include upper concentration limits of biogenic amines. Therefore, a quick and inexpensive way to determine BAs in wine is crucial. A new analytical method based on micellar electrokinetic chromatography has been developed for the separation of the...
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Influence of electropolymerization temperature on corrosion, morphological and electrical properties of PPy doped with salicylate on iron
PublicationIn this work, the influence of the electropolymerization temperature on corrosion, morphological and electrical properties of polypyrrole (PPy) film is studied. Polypyrrole is electrochemically synthesized on iron in the presence of sodium salicylate. The X-ray diffraction and scanning electron microscopy are performed in order to study the structure and morphology of electrodeposited PPy. The electroactive surface area, corrosion...
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Comparative Study of Self-Organizing Maps vs. Subjective Evaluation of Quality of Allophone Pronunciation for Nonnative English Speakers
PublicationThe purpose of this study was to apply Self-Organizing Maps to differentiate between the correct and the incorrect allophone pronunciations and to compare the results with subjective evaluation. Recordings of a list of target words, containing selected allophones of English plosive consonants, the velar nasal and the lateral consonant, were made twice. First, the target words were read from the list by 9 non-native speakers and...
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Comparative analysis of IP-based mobility protocols and fast handover algorithms in IEEE 802.11 based WLANs
PublicationA rapid growth of IP-based networks and services created the vast collection of resources and functionality available to users by means of an uniform method of access - an IP protocol. At the same time, advances in design of mobile electronic devices allowed them to reach utility level comparable to stationary, desktop computers, while still retaining their mobility advantage. Unfortunately, the base IP protocol does not perform...
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A lower bound on the double outer-independent domination number of a tree
PublicationA vertex of a graph is said to dominate itself and all of its neighbors. A double outer-independent dominating set of a graph G is a set D of vertices of G such that every vertex of G is dominated by at least two vertices of D, and the set V(G)D is independent. The double outer-independent domination number of a graph G, denoted by gamma_d^{oi}(G), is the minimum cardinality of a double outer-independent dominating set of G. We...
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Audio codec employing frequency-derived tonality measure
PublicationA transform codec employing efficient algorithm for detection of spectral tonal components is presented. The tonality measure used in MPEG psychoacoustic model is replaced with the method providing adequate tonality estimates even if the tonal components are deeply frequency modulated. The reliability of hearing threshold estimated using psychoacoustic model with standardized tonality measure and the proposed one is investigated...
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The Influence of PEG on Morphology of Polyurethane Tissue Scaffold
PublicationIn this study, polyurethanes (PU) were synthesized from oligomeric dihydroxy(etylene-butylene adipate), poly(ethylene glycol) (PEG), hexamethylene diisocyanate (HDI), 1,4-butanediol (BDO) as chain extender and stannous octoate as catalyst. PEG due to its hydrophilic character influences physical and chemical properties of PU. For testing were used PU having the following weigh contents of PEG: 0%, 7%, and 14%. Porous scaffolds...
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Novel 1,2,4-Oxadiazole Derivatives in Drug Discovery
PublicationAbstract: Five-membered 1,2,4-oxadiazole heterocyclic ring has received considerable attention because of its unique bioisosteric properties and an unusually wide spectrum of biological activities. Thus, it is a perfect framework for the novel drug development. After a century since the 1,2,4-oxadiazole have been discovered, the uncommon potential attracted medicinal chemists’ attention, leading to the discovery of a few presently...
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Measurements of Dispersed Phase Velocity in Two-Phase Flows in Pipelines Using Gamma-Absorption Technique and Phase of the Cross-Spectral Density Function
PublicationThis paper concerns the application of the gamma radiation absorption method in the measurements of dispersed phase velocity in two-phase flows: liquid–gas flow in a horizontal pipe- line and liquid–solid particles in a vertical pipe. Radiometric sets containing two linear 241Am gamma radiation sources and two NaI(Tl) scintillation detectors were used in the research. Due to the stochastic nature of the signals obtained from the...
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Photos and rendered images of LEGO bricks
PublicationThe paper describes a collection of datasets containing both LEGO brick renders and real photos. The datasets contain around 155,000 photos and nearly 1,500,000 renders. The renders aim to simulate real-life photos of LEGO bricks allowing faster creation of extensive datasets. The datasets are publicly available via the Gdansk University of Technology “Most Wiedzy” institutional repository. The source files of all tools used during...
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Zr‐Based Metal‐Organic Framework UiO‐66/Ultem® 1000 Membranes for Effective CO2/H2 Separation
PublicationMixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting...
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Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix
PublicationWe report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydrogen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly(dehydroalanine)-graft-poly(ethyleneglycol) (PDha-g-PEG) in aqueous media. The system shows exceptionally high performance with turnover numbers (TON > 7300) and turnover frequencies (TOF...
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Pyrolysis of RDF and Catalytic Decomposition of the Produced Tar in a Char Bed Secondary Reactor as an Efficient Source of Syngas
PublicationOne of the technical limitations of refuse-derived fuel (RDF) pyrolysis is the high content of tar in its gas products. In order to resolve this problem, a two-stage RDF pyrolysis with a catalyst based on char from RDF pyrolysis is proposed. This paper presents the results of municipal waste pyrolysis beginning in an oven heated to 480 °C and ending with catalytic tar cracking carried out in the temperature range from 800 to 1000...
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Leveraging spatio-temporal features for joint deblurring and segmentation of instruments in dental video microscopy
PublicationIn dentistry, microscopes have become indispensable optical devices for high-quality treatment and micro-invasive surgery, especially in the field of endodontics. Recent machine vision advances enable more advanced, real-time applications including but not limited to dental video deblurring and workflow analysis through relevant metadata obtained by instrument motion trajectories. To this end, the proposed work addresses dental...
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Natural sweeteners: Sources, extraction and current uses in foods and food industries
PublicationFood producers have leaned towards alternative natural and synthetic sweeteners in food formulations to satisfy market demands. Even so, several synthetic sweeteners (e.g., aspartame, saccharin, sucralose) are becoming less popular due to health-related concerns, lower nutritional values, and controversies around their safety. Conversely, natural sweeteners confer favourable customer perceptions due to their association to a healthier...
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The study on the appearance of deformation defects in the yacht lamination process using an AI algorithm and expert knowledge
PublicationThis article describes the application of the A-priori algorithm for defining the rule-based relationships between individual defects caused during the lamination process, affecting the deformation defect of the yacht shell. The data from 542 yachts were collected and evaluated. For the proper development of the algorithm, a technological process of the yacht lamination supported by expert decisions was described. The laminating...
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Natural Deep Eutectic Solvents as Agents for Improving Solubility, Stability and Delivery of Curcumin
PublicationPurpose Study on curcumin dissolved in natural deep eutectic solvents (NADES) was aimed at exploiting their beneficial properties as drug carriers. Methods The concentration of dissolved curcumin in NADES was measured. Simulated gastrointestinal fluids were used to determine the concentration of curcumin and quantum chemistry computations were performed for clarifying the origin of curcumin solubility enhancement in NADES. Results NADES...
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Generalized Pareto ranking bisection for computationally feasible multi-objective antenna optimization
PublicationMulti-objective optimization (MO) allows for obtaining comprehensive information about possible design trade-offs of a given antenna structure. Yet, executing MO using the most popular class of techniques, population-based metaheuristics, may be computationally prohibitive when full-wave EM analysis is utilized for antenna evaluation. In this work, a low-cost and fully deterministic MO methodology is introduced. The proposed generalized...
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Thermal and Hydrodynamic Phenomena in the Stagnation Zone — Impact of the Inlet Turbulence Characteristics on the Numerical Analyses
PublicationOne of the methods of heat transfer enhancement is utilization of the turbulent impinging jets, which were recently applied, for example, in the heat exchangers. Their positive impact on the heat transfer performance was proven, but many questions related to the origin of this impact are still unanswered. In general, the wall-jet interaction and the near-wall turbulence are supposed to be its main reason, but their accurate numerical...
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Improving the Performance of a Graphite Foil/Polyaniline Electrode Material by a Thin PEDOT:PSS Layer for Application in Flexible, High Power Supercapacitors
PublicationIn this study, we present a novel strategy for enhancing polyaniline stability and thus obtaining an electrode material with practical application in supercapacitors. A promising (graphite foil/polyaniline/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) GF/PANI/PEDOT:PSS) electrode material was characterized and used in the construction of a symmetric supercapacitor that provides an outstanding high power density. For this...
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Effect of presence of lifting pocket on the THD performance of a large tilting-pad thrust bearing
PublicationHydrostatic assistance is a commonly used method to improve limited load carrying ability of tiltingpad thrust bearings during transient states of operation of vertical shaft hydro-generators. Despite of special hydraulic equipment (as pumps, valves, etc.), it also requires manufacturing of special recesses/pockets at pad sliding surfaces, into which oil is injected under high pressure. It allows to lift the rotor before start-up...
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Modelling and computer animation of geodetic field work
Publication3D modelling of objects is a way of obtaining information, while the visualization of geospatial data is becoming a production task in the scope of surveying. Visualization of geospatial data provides effective tools for analysis information about the land surface, land cover, its features, properties etc. Computer animations, both 2D images and 3D are becoming additional, expected and clear form for presentation results of geodetic...
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Expression of a GDSL esterase from Pseudomonas sp. S9 in Pichiapastoris
PublicationCold active lipolytic enzymes are promising to replace the conventional enzymes processes of biotechnological industries. One of the most important feature of the cold-active lipases and esterases is that they offer economic benefits through energy saving. In general, they exhibit high activity at low temperatures and low thermostability at moderate temperatures. Lipolytic enzyme EstS9 was isolated from Pseudomonas sp. S9. A multiple...
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Increased concentration of Taq DNA polymerase as a solution for GC-rich templates from clinical and environmental samples
PublicationDNA polymerase is an enzyme which plays crucial role in replication and DNA repair. It found application in PCR (polymerase chain reaction) where catalyses process of in vitro DNA synthesis. To meet the demands posed by mod- ern diagnostic, molecular biology or genetic engineering it is necessary to improve DNA polymerases to obtain new or better features useful in these fields. So far implemented modifications in majority are...
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GPS-derived height changes in diurnal and sub-diurnal timescales
PublicationThis paper describes the research concerning precise short-time GPS solutions conducted in the Centre of Applied Geomatics, Military University of Technology, Warsaw, Poland. The data from ASG-EUPOS (Polish Active Geodetic Network) was processed using Bernese 5.0 software and EPN (EUREF Permanent Network) standards and models. In this study, the adapted 3-hour observation window is shifted every hour for obtaining hourly geocentric...
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Multi-objective design optimization of antenna structures using sequential domain patching with automated patch size deter-mination
PublicationIn this paper, a simple yet efficient and reliable technique for fully automated multi-objective design optimization of antenna structures using sequential domain patching (SDP) is discussed. The optimization procedure according to SDP is a two-step process: (i) obtaining the initial set of Pareto-optimal designs representing the best possible trade-offs between considered conflicting objectives, and (ii) Pareto set refinement...
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Expedited EM-Driven Design of Miniaturized Microwave Hybrid Couplers Using Surrogate-Based Optimization
PublicationMiniaturization of microwave hybrid couplers is important for contemporary wireless communication engineering. Using standard computer-aided design methods for development of compact structures is extremely challenging due to a general lack of computationally efficient and accurate simulation models. Poor accuracy of available equivalent circuits results from neglecting parasitic cross-couplings that greatly affect the performance...
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Remote Stateful Autoconfiguration for Mobile IPv6 Nodes with Server Side Duplicate Address Detection
PublicationDuring interdomain handover, IPv6 node requires new address at its new location. Once the L2 handover procedure is completed, mobile node (MN) starts its IPv6 configuration, using stateless (router advertisements) or stateful (DHCPv6 communication) mode. Once the address is obtained, its uniqueness has to be verified, using Duplicate Address Detection (DAD) procedure. Depending on the interface type, this procedure may easily take...