Search results for: electrodes
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Scaling Up the Process of Titanium Dioxide Nanotube Synthesis and Its Effect on Photoelectrochemical Properties
PublicationIn this work, for the first time, the influence of scaling up the process of titanium dioxide nanotube (TiO2NT) synthesis on the photoelectrochemical properties of TiO2 nanotubes is presented. Titanium dioxide nanotubes were obtained on substrates of various sizes: 2 × 2, 4 × 4, 5 × 5, 6 × 6, and 8 × 8 cm2. The electrode material was characterized using scanning electron microscopy as well as Raman and UV–vis spectroscopy in order...
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The bismuth vanadate thin layers modified by cobalt hexacyanocobaltate as visible-light active photoanodes for photoelectrochemical water oxidation
PublicationBismuth vanadate thin films deposited using the pulsed laser deposition technique were modified using cobalt hexacyanocobaltate (Cohcc). The 2-step method of Cohcc nanocubes preparation was applied: i) metallic cobalt deposition and ii) cobalt electrooxidation in Co(CN)63− containing electrolyte. The presence of CN stretching vibrations was confirmed by Raman spectroscopy. The energy band gap was equal to 2.5 eV and was estimated...
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Evaluation of Three Peptide Immobilization Techniques on a QCM Surface Related to Acetaldehyde Responses in the Gas Phase
PublicationThe quartz-crystal microbalance is a sensitive and universal tool for measuring concentrations of various gases in the air. Biochemical functionalization of the QCM electrode allows a label-free detection of specific molecular interactions with high sensitivity and specificity. In addition, it enables a real-time determination of its kinetic rates and affinity constants. This makes QCM a versatile bioanalytical screening tool for...
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The influence of the welding environment on the properties of Tekken joints made from S355J2C+N steel
PublicationThere are three main methods of underwater welding: dry, wet and intermediate between them, by using the local dry chamber. Due to low costs, the most common method is the wet welding with the use of covered electrodes. Water as a welding environment carries out a lot of problems. The first is limited visibility and instability of the welding arc. The biggest problem during underwater welding is high susceptibility to cold cracking,...
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ReFlexeNN - the Wearable EMG Interface with Neural Network Based Gesture Classification
PublicationThe electromyographic activity of muscles was measured using a wireless biofeedback device. The aim of the study was to examine the possibility of creating an automatic muscle tension classifier. Several measurement series were conducted and the participant performed simple physical exercises - forcing the muscle to increase its activity accordingly to the selected scale. A small wireless device was attached to the electrodes placed...
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Direct brain stimulation modulates encoding states and memory performance in humans
PublicationPeople often forget information because they fail to effectively encode it. Here, we test the hypothesis that targeted electrical stimulation can modulate neural encoding states and subsequent memory outcomes. Using recordings from neurosurgical epilepsy patients with intracranially implanted electrodes, we trained multivariate classifiers to discriminate spectral activity during learning that predicted remembering from forgetting,...
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Nitrogen oxides removal from hydrogen flue gas using corona discharge in marine boilers: Application perspective
PublicationThis paper focuses on the combustion of hydrogen in boilers, as it appears to be a more effective method than using fuel cells for heating purposes due to higher boiler efficiency. One of the main disadvantages of hydrogen combustion in air is NOx formation. Therefore, the authors decided to introduce corona discharge as an inno- vative technique to clean hydrogen flue gas by effectively reducing NOx levels. The method involves...
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Efficiency of pollutants removal from landfill leachates using Nb/BDD and Si/BDD anodic oxidation
PublicationLandfill leachates (LLs) is a complex, refectory and difficult to depurate liquid generated from sanitary landfills. It contains excessive levels of biodegradable and in particular non-biodegradable products (e.g. heavy metals, phenols, sulphide, plasticisers). LLs are among the effluents that may pose major environmental concerns, they can be a dangerous source of pollution e.g. due to infiltration into soil and underlying water....
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Comparison of the effectiveness of automatic EEG signal class separation algorithms
PublicationIn this paper, an algorithm for automatic brain activity class identification of EEG (electroencephalographic) signals is presented. EEG signals are gathered from seventeen subjects performing one of the three tasks: resting, watching a music video and playing a simple logic game. The methodology applied consists of several steps, namely: signal acquisition, signal processing utilizing z-score normalization, parametrization and...
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Role of bead sequence in underwater welding
PublicationThis paper presents examinations of the role of the bead sequence in underwater welding. Two specimens of wet welded layers made by covered electrodes with the use of normalized S355G10+N steel were welded by a reasonable bead sequence. For each specimen, metallographic macro- and micro-scopic tests were done. Then, Vickers HV10 hardness measurements were conducted for each pad weld in the welded layer. The results show that welding...
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Dissimilar underwater wet welding of HSLA steels
PublicationThe high-strength low-alloy S460ML and S460N steels were chosen for underwater wet welding of dissimilar T-joints using covered electrodes. For improving the quality of joints, the temper bead welding (TBW) method was used. The application of TBW in pad welding conditions has been investigated earlier but the possibility of usage of this technique in welded joints was not analyzed. The main aim of the study was to check the influence...
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Electrohydrodynamic Secondary Flow and Particle Collection Efficiency in a One-sided Spike-plate Type Electrostatic Precipitator
PublicationIn this work, results of electrohydrodynamic secondary flow and particle collection efficiency measurements in an electrostatic precipitator under positive and negative voltage polarity are presented. The electrostatic precipitator had two plate collecting electrodes and a single spike discharge electrode. The spike tips were only on one side of the discharge electrode, therefore called a one-sided spike electrode. The electrohydrodynamic...
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Engineering Challenges in the Design of Cochlear Implants
PublicationHearing aids such as cochlear implants have been used by both adults and children for a long time. In addition, cochlear implants are used by patients who have severe hearing loss either by birth or after an accident. This paper aims to investigate the engineering challenges bounding the design of cochlear implants and present its possible solution...
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Electrocatalytic gas sensor with reference layer
PublicationIn recent years electrochemical gas sensors based on solid state electrolytes have been intensively developed. They are easy to obtain, use and relative durable. Nasicon is one of the most promising materials, which have been used in construction of gas sensors. Most of these devices work in potentiometric or amperometric mode. However, some works are dedicated to sensors working in electrocatalytic mode. Principle of operation...
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Non-Contact Monitoring of ECG in the Home Environment—Selecting Optimal Electrode Configuration
PublicationCapacitive electrocardiography (cECG) is most often used in wearable or embedded measurement systems. The latter is considered in the paper. An optimal electrocardiographic lead, as an individual feature, was determined based on model studies. It was defined as the possibly highest value of the R-wave amplitude measured on the back of the examined person. The lead configuration was also analyzed in terms of minimizing its susceptibility...
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Proton-Electron Hole Interactions in Sr(Ti,Fe)O3−δ Mixed-Conducting Perovskites
PublicationOxides in which total electrical conductivity is determined by the partial conductivities of three types of charge carriers i.e. holes/ electrons, oxygen ions, and protons are key components of well-functioning proton ceramic fuel cells. Apart from electrochemical properties also easily modified microstructure is an important feature of the electrodes. In the paper, a group of SrTi1−xFexO3−δ (STF, x = 0.2–0.8) perovskites prepared...
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APPLICATION POSSIBILITIES OF THE S960 STEEL IN UNDERWATER WELDED STRUCTURES
PublicationIn this paper, the application possibilities of the ultra-high strength (UHSS). Domex 960 steel in the underwater welded structures are analyzed. In the research, the investigated material has been tested in bead-on-plate wet welding conditions with the usage of different heat input values, namely 0.63 kJ/mm, 0.72 kJ/mm and 0.93 kJ/mm. Specimens were performed by the manual metal arc (MMA) welding method with the usage of rutile...
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Widespread theta synchrony and high-frequency desynchronization underlies enhanced cognition
PublicationThe idea that synchronous neural activity underlies cognition has driven an extensive body of research in human and animal neuroscience. Yet, insufficient data on intracranial electrical connectivity has precluded a direct test of this hypothesis in a whole-brain setting. Through the lens of memory encoding and retrieval processes, we construct whole-brain connectivity maps of fast gamma (30-100 Hz) and slow theta (3-8 Hz) spectral...
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Tailoring Electro/Optical Properties of Transparent Boron-Doped Carbon Nanowalls Grown on Quartz
PublicationCarbon nanowalls (CNWs) have attracted much attention for numerous applications in electrical devices because of their peculiar structural characteristics. However, it is possible to set synthesis parameters to vary the electrical and optical properties of such CNWs. In this paper, we demonstrate the direct growth of highly transparent boron-doped nanowalls (B-CNWs) on optical grade fused quartz. The effect of growth temperature...
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Badania stabilności chemicznej kompozytowego elektrolitu 3-YSZ-Al2O3 w stosunku do materiałów elektrodowych do zastosowania w średniotemperaturowych ogniwach paliwowych
PublicationJednym z podstawowych wymogów stawianych mate- riałom na elektrolity do średniotemperaturowych ogniw paliwowych IT-SOFC (ang. intermediate-temperature solid oxide fuel cells) jest ich kompatybilność chemiczna z elektrodami w temperaturach zarówno eksploatacji, jak i wytwarzania ogniw. W celu sprawdzenia, czy badany w pracy kompozytowy elektrolit o osnowie z częściowo stabilizowanego ditlenku cyrkonu i z wtrąceniami tlenku glinu...
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MnxCo3-xO4 spinel oxides as efficient oxygen evolution reaction catalysts in alkaline media
PublicationThe design of efficient electrocatalysts for oxygen evolution reaction (OER) is an essential task in developing sustainable water splitting technology for the production of hydrogen. In this work, manganese cobalt spinel oxides with a general formula of MnxCo3-xO4 (x=0, 0.5, 1, 1.5, 2) were synthesised via a soft chemistry method. Non-equilibrium mixed powder compositions were produced, resulting in high electrocatalytic activity....
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Application of BDD thin film electrode for electrochemical decomposition of heterogeneous aromatic compounds
PublicationThe aim of the presented study is to investigate the applicability of electrochemical oxidation of aromatic compounds containing heteroatoms, e.g. waste from production of pesticides or pharmaceutics, at a borondoped diamond (BDD) electrode. The BDD electrodes were synthesized by microwave plasma enhanced chemical vapour deposition (MW PE CVD). Investigation of the electrode surface by optical microscopy and scanning electron microscopy...
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Potentiometric Oxygen Sensor with Solid State Reference Electrode
PublicationThe concentration or the partial pressure of oxygen in an environment can be determined using different measuring principles. For high temperature measurements of oxygen, ceramic-based sensors are the most practical. They are simple in construction, exploration and maintenance. A typical oxygen potentiometric sensor consists of an oxygen ion conducting solid electrolyte and two electrodes deposited...
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Structural and electronic properties of diamond-composed heterostructures
PublicationDiamond is a promising material for 21st century electronics due to its high thermal and electronic conductivity, biocompatibility, chemical stability, high wear resistance, and possibility of doping. However, the semiconductor properties of diamond, especially free-standing films, have not been fully explored. Nor have their integration with polymers and fragile materials and their applications as electronic components. In this...
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Featuring Semitransparent p–i–n Perovskite Solar Cells for High-Efficiency Four-Terminal/Silicon Tandem Solar Cells
PublicationTwo issues need to be resolved when fabricating p–i–n semitransparent perovskite solar cells (ST-PVSCs) for four-terminal (4 T) perovskite/silicon tandem solar cells: 1) damage to the underlying absorber (MAPbI3), electron transporting layer ([6,6]-phenyl-C61-butyric acid methyl ester, PCBM), and work function (WF) modifier (polyethylenimine, PEI), resulting from the harsh sputtering conditions for the transparent electrodes (TEs)...
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Effect of surface on the flexomagnetic response of ferroic composite nanostructures; nonlinear bending analysis
PublicationOur analysis incorporates the geometrically nonlinear bending of the Euler-Bernoulli ferromagnetic nanobeam accounting for a size-dependent model through assuming surface effects. In the framework of the flexomagnetic phenomenon, the large deflections are investigated referring to von-Kármán nonlinearity. Employing the nonlocal effects of stress coupled to the gradient of strain generates a scale-dependent Hookean stress-strain...
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Assessment of organic coating degradation via local impedance imaging
PublicationThe paper presents a new approach to organic coating condition evaluation at micrometer scale using localized impedance measurements. It is based on atomic force microscopy (AFM) in contact mode. Impedance is measured between conductive AFM tip and metal substrate covered with organic coating. A single-frequency voltage perturbation signal is applied between the electrodes and current response signal is registered. As the tip is...
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Methods of trend removal in electrochemical noise data – overview
PublicationIn this paper we shall review popular methods of trend removal from electrochemical noise time records. The basic principles of operation of the six most popular methods are explained. The proposed methods are: high - pass filtering, Moving Average Removal, polynomial detrending, wavelet detrending, Empirical Mode Decomposition and Variational Mode Decomposition. Estimation of trend removal quality...
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Enhanced supercapacitor materials from pyrolyzed algae and graphene composites
PublicationThis study focuses on the synthesis and characterization of supercapacitor materials derived from pyrolyzed natural compounds. Four compounds were investigated: methylcellulose with lysine (ML), methylcellulose with lysine-graphene composite (MLG), algae (A), and algae-graphene composite (AG). The pyrolysis process was utilized to convert these natural compounds into carbon-based materials suitable for supercapacitor applications....
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Controlling crystallites orientation and facet exposure for enhanced electrochemical properties of polycrystalline MoO3 films
PublicationThis study focuses on the development and optimization of MoO3 films on commercially available FTO substrates using the pulsed laser deposition (PLD) technique. By carefully selecting deposition conditions and implementing post-treatment procedures, precise control over crystallite orientation relative to the substrate is achieved. Deposition at 450 °C in O2 atmosphere results in random crystallite arrangement, while introducing...
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Effect of dendrimer-based interlayers for enzyme immobilization on a model electrochemical sensing system for glutamate
PublicationIn this paper, we discuss dendrimer usage in enzyme-based electrochemical biosensors, particularly with respect to biomolecule loading on the sensing surface. A novel approach to design bioactive layers with immobilized enzymes for electrochemical biosensors using the surface plasmon resonance (SPR) method in combination with electrochemical impedance spectroscopy was presented. The gold surface was modified with linear linkers...
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Theoretical designing of selenium heterocyclic non-fullerene acceptors with enhanced power conversion efficiency for organic solar cells: a DFT/TD-DFT-based prediction and understanding
PublicationIn this study, we have designed and explored a new series of non-fullerene acceptors for possible applications in organic solar cells. We have designed four molecules named as APH1 to APH4 after end-capped modification of recently synthesized Y6-Se-4Cl molecule. Density functional theory and time dependent-density functional theory have been employed for computing geometric and photovoltaic parameters of the designed molecules....
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Effect of water salinity on properties of multipass underwater wet manual metal arc welded joints
PublicationThe weldability of steel under the water is limited due to the influence of the environment. Water causes limited visibility, presence of the residual stresses, increasing the cooling rate, and increasing the diffusible hydrogen content in deposited metal, leading to the formation of brittle microstructures in heat-affected zone (HAZ). The paper presents the results of mechanical properties testing of S420G2+M steel welded joints...
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Photoelectrochemically Active N‐Adsorbing Ultrathin TiO2 Layers for Water‐Splitting Applications Prepared by Pyrolysis of Oleic Acid on Iron Oxide Nanoparticle Surfaces under Nitrogen Environment
PublicationHighly performing photocatalytic surfaces are nowadays highly desirable in energy fields, mainly due to their applicability as photo water‐splitting electrodes. One of the current challenges in this field is the production of highly controllable and efficient photoactive surfaces on many substrates. Atomic layer deposition has allowed the deposition of photoactive TiO2 layers over wide range of materials and surfaces. However,...
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Advantages of the Application of the Temper Bead Welding Technique During Wet Welding
PublicationThermo-mechanically rolled S460ML steel was chosen for welding in underwater wet welding conditions by covered electrodes. The main aim of this study was to check the weldability for fillet welds in a water environment by controlled thermal severity (CTS) tests and to check the influence of temper bead welding (TBW) on the weldability of the investigated steel. Non-destructive and destructive tests showed that S460ML steel has...
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Nonlinear impedance as a function of A.C. voltage for glass 40Bi2VO5.5-60SrB4O7 annealed at 473 K for 3h and next fully crystallized measured with impedance spectroscopy method at high temperature region
Open Research DataThe nonlinear electrcial properties as a function of A.C. voltage for annealed at 473 K for 3h and next fully crystallized 40Bi2VO5.5-60SrB4O7 glass was measured by impedance spectroscopy method.
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Smart Weighing Scale with Feet-Sampled ECG
PublicationIn a smart home, health and well-being monitoring systems could be embedded in everyday devices providing a pervasive care. A home bathroom scale is an example of such a device, typically used to measure body weight and very often its composition (e.g. body water/fat percentage). In this paper, we analyzed a potential use of the bathroom scale to measure electrocardiogram (ECG) from electrodes located on the scale's tile. In particular...
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Electrochemical Stability of Few-Layered Phosphorene Flakes on Boron-Doped Diamond: A Wide Potential Range of Studies in Aqueous Solutions
PublicationTwo-dimensional phosphorene has attracted great interest since its discovery as a result of its extraordinary properties. Two-dimensional single crystals of phosphorene can be useful for electrochemical (EC) sensing applications due to their enhanced surface-to-volume ratio. We proposed to investigate the electrochemical performance of phosphorene deposited directly on boron-doped diamond (BDD) electrodes. Noncovalent interaction...
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Enhanced Photoelectrocatalytical Performance of Inorganic-Inorganic Hybrid Consisting BiVO4, V2O5, and Cobalt Hexacyanocobaltate as a Perspective Photoanode for Water Splitting
PublicationThin layers of BiVO4/V2O5 were prepared on FTO substrates using pulsed laser deposition technique. The method of cobalt hexacyanocobaltate (Cohcc) synthesis on the BiVO4/V2O5 photoanodes consists of cobalt deposition followed by electrochemical oxidation of metallic Co in K3[Co(CN)6] aqueous electrolyte. The modified electrodes were tested as photoanodes for water oxidation under simulated sunlight irradiation. Deposited films...
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Noise and Electro-Ultrasonic Spectroscopy of Conducting PolymerThick Films
PublicationThick conducting films based on conducting polymer are characterized by DC conductivity and noise in temperature range 10 to 300 K. Conducting polymers could be used e.g. for the top electrode (cathode) in the solid tantalum or niobium capacitors. On the conducting polymer layer the top layer of carbon/graphite and/or silver polymer based pastes is applied in the capacitor technology. Our samples structure consists of conducting...
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Boron-Enhanced Growth of Micron-Scale Carbon-Based Nanowalls: A Route toward High Rates of Electrochemical Biosensing
PublicationIn this study, we have demonstrated the fabrication of novel materials called boron-doped carbon nanowalls (B:CNWs), which are characterized by remarkable electrochemical properties such as high standard rate constant (k°), low peak-to-peak separation value (ΔE) for the oxidation and reduction processes of the [Fe(CN)6]3–/4– redox system, and low surface resistivity. The B:CNW samples were deposited by the microwave plasma-assisted...
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Visible light activity of pulsed layer deposited BiVO4/MnO2 films decorated with gold nanoparticles: The evidence for hydroxyl radicals formation
PublicationThin films containing BiVO4 and MnO2 deposited on FTO and modified by Au nanoparticles were studied towards their photoelectrochemical and photocatalytical activities in an aqueous electrolyte. Electrodes were prepared by the pulsed laser deposition (PLD) method. The surfactant-free ablation process was used for preparation of the gold nanoparticles (GNP) water suspension. Obtained layers of varied thicknesses (27–115 nm) were...
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Comparison of Classification Methods for EEG Signals of Real and Imaginary Motion
PublicationThe classification of EEG signals provides an important element of brain-computer interface (BCI) applications, underlying an efficient interaction between a human and a computer application. The BCI applications can be especially useful for people with disabilities. Numerous experiments aim at recognition of motion intent of left or right hand being useful for locked-in-state or paralyzed subjects in controlling computer applications....
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Prototype of electrochemical sensor for measurements of volatile organic compounds in gases
PublicationThe paper presents a laboratory prototype of an electrochemical sensor for measurements of volatile organic compounds (VOCs) in gases, utilizing ionic liquids and commercial screen printed electrodes by DropSens. The following ionic liquids have been tested as the electrolyte and redox reaction environment: 1-butyl, 3-methylimidazolium dicyanoamide ([BMIM][N(CN)2]), 1-octyl, 3-methylimidazolium tetrafluoroborate ([OMIM][BF4]),...
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MXene-based composites for capacitive deionization – The advantages, progress, and their role in desalination - A review
PublicationMXenes, a novel large family of 2D transition metal carbides, carbonitrides and nitrides are currently a “hot topic” in science due to their several fascinating physical and chemical properties. It follows from a rich diversity of their elemental compositions and chemical functionalities. MXenes can form composites with many substances, including polymers or metal oxides, which allows to effective “tune” MXene characteristics to...
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Self-assembly of vertically oriented graphene nanostructures: multivariate characterisation by Minkowski functionals and fractal geometry
PublicationThe enormous self-assembly potential that graphene and its derived layered materials offer for responding to the contemporary environmental challenges has made it one of the most investigated materials. Hence, tuning its extraordinary properties and understanding the effect at all scales is crucial to tailoring highly customised electrodes. Vertically oriented graphene nanostructures, also known as carbon nanowalls (CNWs), due...
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Deposition and Electrical and Structural Properties of La0.6Sr0.4CoO3 Thin Films for Application in High-Temperature Electrochemical Cells
PublicationLow-temperature deposition of electroceramic thin films allows the construction of new devices and their integration with existing large-scale fabrication methods. Developing a suitable low-cost deposition method is important to further advance the development of microdevices. In this work, we deposited a 1-lm-thick La0.6Sr0.4CoO3d (LSC) perovskite with high electrical conductivity on sapphire substrates at 400C and analyzed its...
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Improving Accuracy of Contactless Respiratory Rate Estimation by Enhancing Thermal Sequences with Deep Neural Networks
PublicationEstimation of vital signs using image processing techniques have already been proved to have a potential for supporting remote medical diagnostics and replacing traditional measurements that usually require special hardware and electrodes placed on a body. In this paper, we further extend studies on contactless Respiratory Rate (RR) estimation from extremely low resolution thermal imagery by enhancing acquired sequences using Deep...
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A Flexible Nafion Coated Enzyme‐free Glucose Sensor Based on Au‐dimpled Ti Structures
PublicationThe detection of glucose at low concentrations using electrochemical sensors is of great importance due to the possibility of using different human body fluids than blood, such as e.g. urine, saliva, sweat or tears. The interest behind those biofluids is related to their utility in non-invasive sugar determination. In this work, we present flexible, fully biocompatible electrode material based on Au nanoparticles immobilized onto...
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Data Compression in Ultrasonic Network Communication via Sparse Signal Processing
PublicationThis document presents the approach of using compressed sensing in signal encoding and information transferring within a guided wave sensor network, comprised of specially designed frequency steerable acoustic transducers (FSATs). Wave propagation in a damaged plate was simulated using commercial FEM-based software COMSOL. Guided waves were excited by means of FSATs, characterized by the special shape of its electrodes, and modeled...