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Search results for: dissolved oxygen concentration
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Insulin-like growth factor type 2 is better than insulin-like growth factor type 1 a survival marker in patients after acute decompensation of heart failure
PublicationIntroduction:A decreased IGF-1 has been found in heart failure (HF). There are no reports assessing IGF-2 in HF, although in vitro study has shown, that IGF-2 stimulates cardiomyocyte proliferation more than IGF-1. The study aim was to compare the IGF-1 and IGF-2 concentration depending on HF exacerbation and annual survival.Material and methods:Among 75 patients hospitalized...
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Synergistic Effects of Propolis Combined with 2-Phenoxyethanol and Antipyretics on the Growth of Staphylococcus aureus
PublicationThe present investigation aimed to assess the combinational effect of commonly usedantipyretics and antiseptics with ethanolic extracts of propolis (EEPs) on the growth inhibition ofStaphylococcus aureus. The broth microdilution checkerboard assay revealed synergistic interactionsbetween all investigated antipyretics, namely acetylsalicylic acid, ibuprofen, and acetaminophen,with EEPs samples. The values of the fractional inhibitory...
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Electrochemical performance of Co3O4/CeO2 electrodes in H2S/H2O atmospheres in a proton-conducting ceramic symmetrical cell with BaZr0.7Ce0.2Y0.1O3 solid electrolyte
PublicationThe electrochemical performance of Co3O4/CeO2 mixed oxide materials as electrodes, when exposed to H2S/H2O atmospheres, was examined employing a proton conducting symmetrical cell, with BaZr0.7Ce0.2Y0.1O3 (BZCY72) as the solid electrolyte. The impact of temperature (700–850 °C) and H2S concentration (0–1 v/v%) in steam-rich atmospheres (90 v/v% H2O) on the overall cell performance was thoroughly assessed by means of electrochemical...
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The Relationships Between BTEX, NOx, and O3 Concentrations in Urban Air in Gdansk and Gdynia, Poland
PublicationThis paper presents the results of atmospheric air quality research conducted in the areas of two shipyard cities: Gdansk and Gdynia (Poland), in the period between March and December 2011. The purpose of the research was focused on determination of benzene, toluene, ethylbenzene, and xylenes (BTEX) compounds in atmospheric air. Passive sampling technique, with Radiello® diffusive passive samplers, was used for BTEX sample collection...
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A pin-on-disc study of airborne wear particle emissions from studded tyre on concrete road contacts
PublicationStudded tyres wear surfaces of winter roads, generating inhalable airborne particles. In this study, four concrete road materials and two stud geometries were investigated in terms of wear, road material hardness and airborne particle concentration. The sliding contact between studded tyres and road materials was studied using a pin-on-disc machine in a clean chamber. The results show that the normal load and the stud size have...
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Effect of Laminar Pulsatile Fluid Flow on Separation of Volatile Organic Compounds from Aqueous Solution by a Hollow Fiber Membrane-Based Process
PublicationIn this study, a laminar pulsatile fluid flow was used for the separation of benzene, toluene, ethylbenzene, and xylene isomers (BTEX) from aqueous solutions. Polyether sulfone hollow fiber membrane has been applied to this process. The effects of BTEX concentration, and feed and extraction flow rates were examined. It was found that the application of the pulsatile fluid flow with...
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Równolegle przebiegające procesy separacji pianowej jonów Al(III), Cu(II) i Zn(II) z roztworów ich mieszanin
PublicationMetody flotacji jonowej i precypitacyjnej należą do procesów separacji pianowej, wykorzystujących zdolność selektywnej adsorpcji niektórych składników roztworu na powierzchni międzyfazowej gaz – ciecz. Do zalet separacji pianowej zalicza się m.in. niewysokie koszty inwestycyjne i eksploatacyjne oraz wysoką skuteczność w obróbce roztworów rozcieńczonych. Celem pracy jest ocena wpływu kluczowych parametrów na wydajność i przebieg...
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Double layer adhesive silicone dressing as a potential dermal drug delivery film in scar treatment
PublicationThe present studies focused on the evaluation of design of an adhesive silicone film intended for scar treatment. Developed silicone double layer film was examined in terms of its future relevance to therapy and applicability on the human skin considering properties which included in vitro permeability of water vapor and oxygen. In order to adapt the patches for medical use in the future there were tested such properties as...
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Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublicationHydrolysis is an important process in biological wastewater treatment and is known to be the ratelimiting step in organic carbon removal from municipal or industrial wastewater. The influence of the readily biodegradable chemical oxygen demand fraction in biological wastewater treatment systems has been extensively investigated, but little is known about the effects of slowly biodegradable substrate (XS) on denitrification and...
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Reliability and efficiency of pollution removal during long-term operation of a one-stage constructed wetland system with horizontal flow
PublicationThe paper presents the results of a study of the reliability and efficiency of pollutant removal during long term operation of a one-stage constructed wetland system with horizontal flow. The flow rate of the wastewater treatment plant was 1.2 m3·d-1 during the research period. Physical and chemical analyses of raw wastewater and treated effluent were carried out in the years 1997–2010 (14 years). During this study period, 56 series...
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The evaluation of COD fractionation and modeling as a key factor for appropriate optimization and monitoring of modern cost-effective activated sludge systems
PublicationA study was conducted to characterize the raw wastewater entering a modern cost effective municipal WWTP in Poland using two approaches; 1) a combination of modeling and carbonaceous oxygen demand (COD) fractionation using respirometric test coupled with model estimation (RTME) and 2) flocculation/filtration COD fractionation method combined with BOD measurements (FF-BOD). It was observed that the particulate fractions of COD obtained...
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The Influence of COD Fraction Forms and Molecules Size on Hydrolysis Process Developed by Comparative OUR Studies in Activated Sludge Modelling
PublicationThe activated sludge models (ASMs) commonly used by the International Water Association (IWA) task group are based on chemical oxygen demand (COD) fractionations. However, the proper evaluation of COD fractions, which is crucial for modelling and especially oxygen uptake rate (OUR) predictions, is still under debate. The biodegradation of particulate COD is initiated by the hydrolysis process, which is an integral part of an ASM....
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Study of the Resistance to Influence of Aggressive Liquids on Concrete with Lightweight Aggregate
PublicationThe corrosion of the structure of concrete caused by the aggressive external environment is one of the main problems that can reduce the durability of buildings. The paper analyzes the influence of the type of component on selected properties of lightweight concrete (LWC) exposed to aggressive liquids. When lightweight concrete containing porous aggregates is used, the influence of an aggressive environment may be of particular...
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Experimental Study of the Resistance to Influence of Aggressive Liquids on Lightweight Concrete
PublicationIn light of the scientific research, the corrosion of concrete structures is one of the main problems that may reduce their durability due to the negative impact of the natural environment. The paper analyzes the influence of the type of component on the selected properties of lightweight concrete subjected to the influence of aggressive liquids. Four concrete mixes were prepared with a granular aggregate made of foamed glass (GEGA)...
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Attenuation of Hyperglycemia in Diabetic Rats Assisted by Immobilized Probiotic in Sodium Alginate
PublicationDiabetes mellitus type 2 (DM2) is the most common chronic disease worldwide, characterized mainly by increased glucose concentration in the blood and affecting several organs’ functionality. The daily consumption of probiotic bacteria can help control diabetes and reduce the damage caused. Cell immobilization techniques are a powerful tool that provides physical cell protection to such probiotic bacteria against gastrointestinal...
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Selektywne chłodzenie mózgu noworodka po niedotlenieniu okołoporodowym. Cześć 3. Hybrydowy system selektywnego chłodzenia mózgu noworodka
PublicationZapoczątkowane brakiem tlenu procesy biochemiczne mają zgubne skutki dla układu nerwowego, w szczególności rozwijającego się. Hipotermia, czyli stan oziębienia poniżej pewnych wartości temperatur, spowalnia znacznie lub całkowicie wyhamowuje poszczególne reakcje, i to leży u podstaw jej własności neuroprotekcyjnych. Powyższe twierdzenie poparte licznymi faktami naukowymi leży u podstaw koncepcji selektywnego chłodzenia mózgu i...
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Charakterystyka odcieków powstających w aspekcie wyboru metody ich oczyszcania
PublicationArtykuł obejmuje analizę odcieków generowanych w zakładach utylizacji odpadów w aspekcie ich ilości i jakości oraz możliwości oczyszczania/zagospodarowania, ze szczególnym zwróceniem uwagi na metody biologiczne, najbardziej przyjaznej środowisku. Ponad trzyletnie badania prowadzono na dwóch obiektach zlokalizowanych w woj. pomorskim, gdzie pobierano próbki ścieków technologicznych, powstających podczas sortownia oraz kompostownia odpadów...
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Simultaneous Removal of Al, Cu and Zn Ions from Aqueous Solutions Using Ion and Precipitate Flotation Methods
PublicationThis paper presents the results of investigations concerning the simultaneous removal of Al(III), Cu(II), and Zn(II) from dilute aqueous solutions using ion and precipitate flotation methods. The effects of initial solution pH, surface active substance concentration, and the gas velocity on the flotations’ efficiency and course are studied. Experimental results are discussed in terms of physicochemical aspects related to aqueous...
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Al(III) and Cu(II) simultaneous foam separation: Physicochemical problems
PublicationSimultaneous removal of Al(III) and Cu(II) from dilute aqueous solutions by ion and precipitate flotation methods is investigated. Influence of the pH of the initial solution, the surface active collector concentration and the gas flow rate on the final removal ratio and the course of ion and precipitate flotations is presented. Results show that simultaneous flotations of Al(OH)3 and Cu(OH)2 insoluble species occur allowing to...
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Influence of terpenes on indoor air quality
PublicationThe aim of this study was to investigate air quality in hairdresser salons, focusing on terpenes determination. Terpenes are known reactive volatile organic compounds that contribute to secondary organic aerosol formation. Those compounds are frequently found in cosmetic products as fragrance agents. Hairdresser salons are special kind of environment, where secondary organic aerosol concentration may be elevated. One hairdresser...
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Identification of volatile compounds based on the electrocatalytic gas sensor responses
PublicationMeasured response in case of electrocatalytic gas sensors is in form of a voltamperometric characteristic. Current-voltage (I-V) response shape depends on the gas type and its concentration. Such response contains significantly more information comparing with typical electrochemical sensors, but is quite difficult to analyze. When I-V curve contains current peaks, position of such peaks can be used...
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Performance of the flat plate solar collector operated with water-Al2O3 nanofluid
PublicationThe paper discusses the effect of application of water-Al2O3 nanofluid, as a working fluid, on the efficiency of a flat plate solar collector. The mass concentration of nanoparticles was 0.1%, 0.2% and 0.4%. The tests were conducted for two values of radiation of about 1050 W/m2 and 400 W/m2, and volume flow rates of 60 l/h, 120 l/h and 170 l/h. The efficiency was calculated according to recommendations of the Polish Standard....
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Degradation of cefadroxil drug by newly designed solar light responsive alcoholic template-based lanthanum ferrite nanoparticles
PublicationIn this work, lanthanum ferrite nanoparticles were synthesized via a simple co-precipitation method. Two different templates, namely sorbitol and mannitol, were used in this synthesis to tune the optical, structural, morphological, and photocatalytic properties of lanthanum ferrite. The synthesized lanthanum ferrite-sorbitol (LFOCo-So) and lanthanum ferrite-mannitol (LFOCo-Mo) were investigated through Ultraviolet–Visible (UV–Vis),...
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Potential fertilizing properties of sewage sludge treated in the Sludge Treatment Reed Beds (STRB)
PublicationIn research the fertilizer value of sludge from reed beds is evaluated based on the sampling sludge on different depths from 4 Danish STRB after long periods of stabilization. The dewatering efficiency of sewage sludge in the STRB is comparable to mechanical dewatering. The long-term stabilization of sewage sludge progressively decreases the concentration of organic matter due to the process of humification. The aim of the work...
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Porównanie efektywności biologicznego usuwania związków biogennych w procesach MUCT i A2/O na przykładzie oczyszczalni w Gdańsku
PublicationThis paper presents a comparison of the efficiency of nutrient removal in two different technological systems functioning in WWTP in Gdansk. The upgrade was necessary in order to adjust the parameters of wastewater treatment to more stringent requirements for Total Nitrogen removal (Total Nitrogen concentration < 10 mg/L). Since 2012 the biological treatment line has operated based on modified A2/O process instead of MUCT process....
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Sample preparation techniques for determination of pesticide residues in food samples
PublicationPesticides are very important in increasing the efficiency and quality of agricultural production. They are applied in many spheres of life, not only in agriculture, and their applications are expanding. Despite their numerous merits, pesticides are some of the most toxic substances contaminating our environment and have a negative impact on the human health. Properties of pesticides such as stability, ability to bioaccumulation...
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In situ study of a composition of outlet gases from biogas fuelled Solid Oxide Fuel Cell performed by the Fourier Transform Infrared Spectroscopy
PublicationThe purpose of this study was to develop a method and software based on the Fourier Transform Infrared Spectroscopy for the in-situ, quantitative analysis of the composition of outlet gases from Solid Oxide Fuel Cell (SOFC). The calibration procedure performed at the beginning of the experiment indicated a polynomial dependence between the concentration of a calibrating gas (CO, CO2, CH4) and the corresponding integrated absorbance in...
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Effect of Ethanol Extracts of Propolis (EEPs) against Staphylococcal Biofilm—Microscopic Studies
PublicationStaphylococci growing in the form of biofilm exhibit high resistance to a plethora of antibiotics. The aim of the study was to assess the influence of ethanolic extract of propolis (EEPs) on S. epidermidis ATCC 35984 biofilm using fluorescent microscopy. Propidium iodide (PI) and SYTO 9 were used for differentiation of live and dead cells, and calcofluor white was used to stain the extracellular matrix, the self-produced extracellular...
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Removal of Arsenic from Wastewater Using Hydrochar Prepared from Red Macroalgae: Investigating Its Adsorption Efficiency and Mechanism
PublicationArsenic (As) is a prominent carcinogen component produced via both geogenic and anthropogenic processes, posing serious risks to human health. This study aimed to investigate the potential of hydrochar prepared from red macroalgae for removing As from synthetic wastewater. The hydrochar was produced through 5 h hydrothermal carbonization (HTC) treatment at 200 °C, and then, chemically activated with ferric chloride hexahydrate...
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Pre-treatment of bio fraction waste prior to fermentation processes
PublicationCurrent efforts are taken to increase resource efficiency, close material loops, and improve sustainable waste and by-products management. Thus, networking agro-food by-products and converting them into valuable products completely exhausting the potential of the raw material becomes significant. Model lignocellulosic and starch based biomass were subjected to pre-treatment with the application of acidic compounds, i.e. sulphuric...
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A competition between two- and three-body dissociation channels in photo-double-ionization of tetrahydro-2H-pyran and 3,4-dihydro-2H-pyran molecules
PublicationVarious molecules possess structures consisting of the heterocyclic rings containing oxygen atoms. These substances often play a significant role in many different fields of chemistry, medicine, and biology. Due to a specific atomic composition and bond arrangement, many of these molecules retain unique electronic properties, which may be probed by diverse spectroscopic techniques, including those utilizing synchrotron radiation....
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9 - Solid oxide fuel and electrolysis cells
PublicationIn this chapter, the fundamental reactions, the geometrical designs, the material requirements, and the status of SOFCs and SOECs are presented. In the following seven chapters, the most important components of an SOC are described and the chapter ends with a summary and outlook. The described components are: (i) oxygen-ion conductors (electrolyte), (ii) anode materials for SOFCs (cathode in SOEC mode), (iii) cathode materials...
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Modelling of Diffusing Capacity Measurement Results in Lung Microangiopathy Patients. A novel Diagnostic Suppport
PublicationLung microangiopathy is a little known negative influence of diabetes mellitus on the functioning of the lungs. The aim of this study is to design a supportive method for diagnosing lung microangiopathy. This will be based on routinely performed pulmonary measurements as well as on investigation process modelling and data processing. A model of the diffusion of oxygen from the alveoli to the blood has been described with a set...
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Surface modifcation of PMMA polymer detected by XPS
Open Research DataIn order to obtain the experimental specimens, four PMMA/PC61BM samples with the following mass proportions were prepared: 10%, 20%, 30%, and 40%. In addition, as a reference, a PMMA sample without PC61BM was prepared as well. For the fabrication process, PC61BM 99.5% (Solenne BV), chloroform HPLC (Sigma Aldrich), and PMMA (commercially available...
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Dynamic impedance data for various carboxylic acids corrosion inhibition of aluminium in alkaline media (pH=11)
Open Research DataThis dataset contains the results of Dynamic Electrochemical Impedance Spectroscopy (DEIS) carried out in galvanostatic mode under iDC=0, carried out in order to define the corrosion inhibition effect of various studied carboxylic acids: citric acid, malic acid, maleic acid, succinic acid, tartaric acid, carballylic acid, and serine. The experiment...
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Structure of ammonium vanadate synthesis by LPE-IonEx method
Open Research DataThe DataSet contains the XRD patterns, FTIR spectra of NH4VO3 crystals with different morphology obtained by the LPE-IonEx method.
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Transport properties of aqueous ionic liquid microemulsions: influence of the anion type and presence of the cosurfactant
PublicationTransport properties, viz. specific conductivity, dynamic viscosity and apparent diffusion coefficients, were measured as a function of water content in aqueous ionic liquid microemulsions containing 1-butyl-3- methylimidazolium hexafluorophosphate, [BMIM][PF6] and bis(trifluoromethanesulphonyl)imide, [BMIM][Tf2N], stabilized by the nonionic surfactant TX-100, or its mixture with a cosurfactant, i.e. butanol. The investigation covered...
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Organic semiconductor rubrene thin films deposited by pulsed laser evaporation of solidified solutions
PublicationOrganic semiconductor rubrene (C42H28) belongs to most preferred spintronic materials because of the high charge carrier mobility up to 40 cm2(V·s)-1. However, the fabrication of a defect-free, polycrystalline rubrene for spintronic applications represents a difficult task. We report preparation and properties of rubrene thin films deposited by pulsed laser evaporation of solidified solutions. Samples of rubrene dissolved in aromatic...
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Ellipsometric study of carbon nitride films deposited by DC-magnetron sputtering
PublicationWe report the optical properties of a carbon nitride (CNx) film as a function of nitrogen concentration (N/C) of the deposited film. As nitrogen concentration is increased (N/C ratio) in a CNx film, the refractive index and band gap also increase. The real and imaginary parts, n and k (refractive index and extinction coefficient) of the complex refraction index of carbon nitride films were determined by spectroscopic ellipsometry...
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Sessile droplet contact angle of water–Al2O3, water–TiO2 and water–Cu nanofluids
PublicationThis work presents measurements of the contact angle of sessile droplets for three nanofluids, i.e. water–Al2O3, water–TiO2 and water–Cu. The plates made of glass, anodized aluminium and stainless steel of different roughness served as substrates. Ultrasonic vibration was used for 30–60 min in order to stabilise the dispersion of the nanoparticles. Nanoparticles were tested at the concentration of 0.01%, 0.1%, and 1% by weight....
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Application of analytical procedure based on accelerated solvent extraction and ion chromatography technique for determination of thiocyanate and other inorganic ions in human placenta samples
PublicationExposure of a pregnant woman during pregnancy is a special case of exposure to toxic substances. Samples of placenta collected for the studies had been prepared with the technique of accelerated solvent extraction and later analyzed for the presence of thiocyanate ion and other inorganic ions, with the use of the technique of ion chromatography. The concentration of thiocyanate ion in placenta samples collected from active smokers...
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Sustainable recovery of plant essential Nitrogen and Phosphorus from human urine using industrial coal fly ash
PublicationCoal-based thermal power plants play a pivotal role in meeting global energy demand. The amount of fly ash generated from these plants increases every year, and its successful use has posed a significant environmental risk in the last decade. In this study, coal fly ash was packed in a fixed-bed adsorption column to remove Urea–N from synthetic human urine. To assess the efficacy of fly ash in the removal of Nitrogen, various process...
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Freshening of salinized groundwater in Gdańsk Quaternary aquifer
PublicationThe main Quaternary aquifer in the Gdańsk region connects directly with salt waters of the Martwa Wisła River and the Gulf of Gdańsk. This aquifer has been used for many years by large municipal and industrial intakes located on the marine lowlands, with maximum output 6236 m3 /h in 1985. Owing to an intensive exploitation, groundwater in the area of the Old Gdańsk has been salinized by intrusion of salt water from the Martwa Wisła...
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PRELIMINARY RESULTS FROM APPLICATION PHOSLOCK® TO REMOVE PHOSPHORUS COMPOUNDS FROM WASTEWATER
PublicationThe aim of the study is to assess the removal effectiveness of phosphorus compoundsby using lanthanum-modified bentonite. This material was produced by the Australian company Phoslock® Water Solutions Pty Ltd. According to the company, Phoslock® has substantial capacity to bound phosphate anions. The investigation was carried out in steady conditions in laboratory model with beakers. The results of the study are related to the...
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Studies on Treatment of Bitumen Effluents by Means of Advanced Oxidation Processes (AOPs) in Basic pH Conditions
PublicationThe paper presents the results of studies on chemical treatment of effluents from production of bitumen of petroleum origin. Due to the presence of sulfide ions, the pH of these effluents is strongly alkaline. Several Advanced Oxidation Processes (AOPs) were studied, including the use of hydroxyl and sulfate radicals oxidants, the hydrodynamic cavitation as well as sonocavitation. The best processes allow to obtain 45% reduction...
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Studies on treatment of bitumen effluents by means of Advanced Oxidation Processes (AOPs) in basic pH conditions
PublicationThe paper presents the results of studies on chemical treatment of effluents from production of bitumen of petroleum origin. Due to the presence of sulfide ions, the pH of these effluents is strongly alkaline. Several Advanced Oxidation Processes (AOPs) were studied, including the use of hydroxyl and sulfate radicals oxidants, the hydrodynamic cavitation as well as sonocavitation. The best processes allow to obtain 45% reduction...
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Influence of reduction process on the structural and mechanical properties of (Pb,Bi)-(Si,Ge)-O oxide glasses
PublicationThe effect of the reduction process in H2 at 380 °C on the microstructure and elemental composition of a glass Bi0.4Pb0.2Si0.4Ox has been investigated. It has been shown that after reduction a clearly separated top layer with a thickness of approx. 50 µm was formed on the surface of the sample. This layer is depleted of oxygen and has higher electrical conductivity than the interior of the glass. It has also been found that some...
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Antioxidants: a premature scientific hypothesis that reshuffled the traditional food pyramid
PublicationAntioxidants present in substantial amounts in foods, plant-based products in particular, have been suggested as chemopreventive agents that can curb the development of undesirable health effects caused by oxidative stress simply by enriching diet in such compounds. This idea has been enthusiastically accepted by consumers, as well as food and pharmaceutical industry, and created great demand for products containing antioxidant...
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Wpływ procesu redukcji na właściwości strukturalne i mechaniczne szkieł tlenkowych z grupy (Pb,Bi)-(Si,Ge)-O = Influence of reduction process on the structural and mechanical properties of (Pb,Bi)-(Si,Ge)-O oxide glasses
PublicationThe effect of the reduction process in H2 at 380 °C on the microstructure and elemental composition of a glass Bi0.4Pb0.2Si0.4Ox has been investigated. It has been shown that after reduction a clearly separated top layer with a thickness of approx. 50 µm was formed on the surface of the sample. This layer is depleted of oxygen and has higher electrical conductivity than the interior of the glass. It has also been found that some...
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The SARS‐CoV ‐2 specific IgG antibodies biophotonic sensor
PublicationIn this paper, we present the design and the principle of operation of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) specific immunoglobulin G (IgG) biophotonic sensor, which is based on the single-mode telecommunication fiber. We fabricated the sensor head at the face of the single mode fiber-28. Due to the process of bio-functionalization, our sensor has the ability to selectively detect the SARS-CoV-2 specific...
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Deep eutectic solvents based assay for extraction and determination of zinc in fish and eel samples using FAAS
PublicationA new assay based on effective (high recovery) extraction by means of deep eutectic solvents (DESs) was developed for ppb level determination of zinc in fishes and eel samples. Choline chloride and Phenol in a 1:2 M ratio was selected as optimal DES-based extraction solvent. 8-Hydroxy quinoline was used as a chelating agent for zinc ions. The optimized conditions were found at pH value of 8, ligand concentration of 10 mg/L, THF...
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Ultrasound-assisted deep eutectic solvent-based liquid–liquid microextraction for simultaneous determination of Ni (II) and Zn (II) in food samples
PublicationA new approach was developed for the simultaneous pre-concentration and determination of Ni (II) and Zn (II) in food samples. This method is based on ultrasound-assisted liquid–liquid micro extraction using hydrophobic deep eutectic solvent (DES) and 1,10-phenanthroline as chelating agent. The effect of several parameters, such as pH, selection and volume of DES, amount of chelating agent, time of sonication and centrifugation,...
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Application of Electronic Nose to Ambient Air Quality Evaluation With Respect to Odour Nuisance in Vicinity of Municipal Landfills and Sewage Treatment
PublicationThis chapter contains information about application of the electronic nose type instruments to evaluation of ambient air odour quality connected with such sectors of human activity as municipal landfills or sewage treatment plants. The authors present potential sources of emission from these sectors, characterize the chemical compounds responsible for presence of unpleasant odours, describe the influence of those compounds on human...
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Complementary Use of Multi-dimensional Gas Chromatography and Proton Transfer Reaction Mass Spectrometry for Identification of Rapeseed Oil Quality Indicators
PublicationThe change of concentration of various volatiles generated during frying may be an indicator of oil quality. Chemical compounds such as aldehydes, ketones, alcohols and carboxyl acids are the products of oxidation during thermal degradation of edible oils. Shown in this work is a complementary use of GC×GC-TOFMS and PTR-MS for the detection and determination of quality indicators of rapeseed oil. The former technique was used for...
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Impact of Volcanic Eruptions on the Occurrence of PAHs Compounds in the Aquatic Ecosystem of the Southern Part of West Spitsbergen (Hornsund Fjord, Svalbard)
PublicationThe paper presents changes in concentration levels of dioxin-like compounds that can be observed over the course of four study seasons in water samples collected from the Arctic watershed of Svalbard. The conducted analysis involved anthropogenic and natural factors that may affect the concentration of PAHs in the study samples of water. An attempt is made to indicate the emission source of the compounds being deposited and to...
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Numerical simulation of natural convection of Glycol-Al2O3 nanofluids from a horizontal cylinder
PublicationThis paper deals with natural convection around a circular cylinder with constant heat flux in a cavity using computational fluid dynamics. As fluids ethylene glycol and a mixture of ethylene glycol with Al2O3 nanoparticles (mass concentrations of nanoparticles: 0.1% and 1%) are chosen. Rayleigh number ranges from 3104 to 3105. The nanofluids are modeled with single-phase approach. For the investigated range of nanoparticle concentration, the...
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Comparative Study of Balancing SRT by Using Modified ASM2d in Control and Operation Strategy at Full-Scale WWTP
PublicationDetailed knowledge on the composition of the influent going into the wastewater treatment system is essential for the development of a reliable computer model. In the context of WWTPs (wastewater treatment plants), the wastewater characteristics are not only important for activated sludge system modelling, but also have an impact on the appropriate control of single unit operations. The aim of this study was to evaluate the concepts...
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The presence of polycyclic aromatic hydrocarbons in disposable baby diapers: A facile determination method via salting-out assisted liquid-liquid extraction coupled with gas chromatography-mass spectrometry
PublicationIn this paper we demonstrate the development of the extraction procedure of polycyclic aromatic hy- drocarbons from baby diapers along with their quantification by gas chromatography-mass spectrometry. Apart from covering plastic foil, disposable baby diapers contain sorbents intended to absorb urine and feces. A hygroscopic, adsorptive, and tough-to-homogenize fibrous sorbent, represents an analytical chal- lenge to analytical...
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Hybrid metal and non-metal activation of Oxone by magnetite nanostructures co-immobilized with nano-carbon black to degrade tetracycline: Fenton and electrochemical enhancement with bio-assay
PublicationElectrochemically synthesized magnetite nanostructures (ESMNPs) as a metal activator and nano-carbon black (NCB) as a non-metal activator were co-immobilized by alginate natural polymer to activate Oxone for the degradation of tetracycline (TC) antibiotic. The formation of sulfate radical was indirectly confirmed during the Oxone/ESMNPs/NCB/alginate process via the addition of scavenging compounds. This study revealed the high...
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Expression of cyclin D1 after treatment with doxorubicin in the HL-60 cell line
PublicationIncreased levels of cyclin D1 and amplification of CCND1 gene occur in many types of cancers. We have followed the expression of cyclin D1 after treatment with doxorubicin with reference to cell death and other possible therapeutic implications. The effect of the treatment on the cell cycle, survival, intracellular level (flow cytometry), and intracellular localization of cyclin D1 (fluorescence microscopy) and expression of...
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Human serum interactions with phenolic and aroma substances of Kaffir(Citrus hystrix) and Key lime (Citrus aurantifolia) juices
PublicationTo understand the therapeutic application of polyphenols extracted from Kaffir (PolKaf) and Key (PolKey) limesdifferent analytical methods were applied. Based on quantitative analysis by two dimensional gas chromato-graphy (GC×GC) and time of flight mass spectrometry (TOFMS) it can be observed that the biggest differencesin the contents of selected terpenes of Kaffir and Key limes occur in chemical compounds such as limonene, citraland...
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Development Of Dynamic Method For Evaluation Of Corrosion Rate On The Example Of Organic Corrosion İnhibitor
PublicationMeasurements of the corrosion rate belong to the most important aspects of materials science. In order to reduce material loss corrosion inhibitors are used. However selection of proper inhibitor should be based on evaluation of its mechanism and effective concentrations. Mechanism of inhibition usually has dynamic character so physicochemical parameters are changing in time. Most of actually used methods...
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Monitoring of lysozyme thermal denaturation by volumetric measurements and nanoDSF technique in the presence of N-butylurea
PublicationThe results of thermal studies of denaturation of hen egg white lysozyme (HEWL) in water and an aqueous solution of N-butylurea (BU) are presented. High-precision densimetric measurements were used to characterize and analyze the changes of the specific volume, v, during temperature elevation. The temperature of the midpoint of protein denaturation was also determined by nanoDSF technique (differential scanning fluorimetry). The...
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Rheology of potato starch chemically modified with microwave-assisted reactions
PublicationNative potato starch was sulfated, selenated, borated, silicated and zincatated by means of microwave-assisted reactions with varying doses of relevant reagents. Resulting products were characterized involving rheological behavior of pastes, their weight-average molecular weight (Mw), and radius of gyration (Rg). Most of the pastes showed shear-thinning behavior, with the flow behavior index (n) below unity. The pastes of starch...
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TEM and EDX study of the Al2O3 ultra thin films
Open Research DataThe ultra-thin layers of Al2O3 were deposited on a silicon substrates. The method of atomic layer deposition (Beneq TFS 200 ALD system) was chosen as the proper method of dielectric layer deposition. This method provides precise thickness control down to a single atomic layer. The precursors used were trimethylaluminum (Sigma-Aldrich) and purified water....
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Reply to Comment on ‘Nanodiamond incorporated human liver mimicking phantoms: prospective calibration medium of magnetic resonance imaging’
PublicationDependence of the spin–lattice (T1) relaxation times on the nanodiamond concentration in human liver phantoms is discussed. Factors affecting stability and and reproducibility of these phantoms are presented. The need for comparative measurements on multiple MRI scanners for better understanding of potential variations in the obtained imaging data is emphasised.
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Thermogravimetric analysis data of hydration in air and nitrogen for BaCe0.6Zr0.2Y0.1M0.1O3-δ (M = Fe, Pr, Tb)
Open Research DataThe dataset consists of 6 files of thermogravimetric analysis (TGA) data. The TGA experiments of hydration for BaCe0.6Zr0.2Y0.1Fe0.1O3-δ (BCZYFe), BaCe0.6Zr0.2Y0.1Pr0.1O3-δ (BCZYPr), and BaCe0.6Zr0.2Y0.1Tb0.1O3-δ (BCZYTb) were conducted on Netzsch STA 449.
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Testing of DES toxicity towards Candida subhashii
Open Research DataDataset presents results of testing toxicity of selected DES solutions in mineral salt medium towards Candida subhashii.
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FTIR spectra and IGC chromatograms for chemically reduced graphene oxide aerogels (rGOA)
Open Research DataThe effect of selected synthesis parameters on reduced graphene oxide aerogels properties was investigated using Fourier-transform infrared spectroscopy and dynamic adsorption method (Inverse Gas Chromatography, IGC). Samples were synthesized by sol-gel method by reduction induced self-assembly of graphene oxide. As a reductant l-ascorbic acid was used....
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X-ray Photoelectron Spectroscopy studies of various carboxylic acids adsorption on aluminium alloys in alkaline media
Open Research DataThis dataset contains the results of high-resolution XPS studies obtained during evaluation of high corrosion inhibition efficiency of various carboxylic acids towards aluminium alloy 5754 in bicarbonate buffer pH=11.
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Anaerobic consortia mediate Mn(IV)-dependent anaerobic oxidation of methane
PublicationManganese-dependent anaerobic oxidation of methane (Mn-AOM) is a major methane sink and vital to mitigating global warming. However, it is difficult for microorganisms to mediate electron transfer between the hardly dissolved CH4 and insoluble Mn(IV) minerals, leading to poor understanding of species mediating Mn-AOM. This study successfully enriched an anaerobic consortium mediating AOM driven by Mn-dependent respiratory growth,...
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Role of the Lakes in Groundwater Recharge and Discharge in the Young Glacial Area, Northen Poland
PublicationThe aim of this research was to delineate characteristic hydrogeological lake types in the Young Glacial Area (YGA). The YGA is in the central and east part of the Kashubian Lake District (KLD) in Northern Poland, an area covered by deposits of Quaternary glaciation. All the bigger lakes were investigated in the area of about 1500 km2 (39 lakes). The role of lakes in groundwater recharge and discharge was determined from total...
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Noise related to gas bottles explosions
PublicationModern industrialized world is in a never ending danger of accidents and catastrophes of technical nature. Some of them may involve fires and explosions of gas storage bottles or containers. Technical University of Gdansk, Poland performed numerous tests where bottles containing acetylene, oxygen, hydrogen, CO2, LPG, LNG or CNG were blown due to excessive temperature caused by fire. Although those experiments were not focused on...
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Synthesis and Spectroscopic Properties of New Bis-tetrazoles
PublicationSyntheses of N,N'-phenyltetrazole podands link with aliphatic chains containing oxygen, nitrogen and sulphur atoms, are described. The complexing properties of these compounds towards metal cations (Fe2+, Cu2+, Zn2+, Co2+, Ni2+) were investigated by absorption and infrared spectroscopy. The UV-Vis titrations were performed to estimate the stability constant values of the respective complexes with Cu2+ ion. Changes in UV-Vis absorption...
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The Role of Proteins in Food
PublicationThis chapter describes the effect of proteins on the sensory attributes and the biological value and safety of foods. The role of proteins depends on their amino acid composition and structure, on changes due to storage and processing, as well as on interactions with other food components. The effect on the sensory quality of foods is brought about by hydrophobicity, solubility, water holding capacity, gelling, film formation,...
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Method of selecting the LS-SVM algorithm parameters in gas detection process
PublicationIn this paper we showed the method of resistive gas sensors data processing. The UV irradiation and temperature modulation was applied to improve gas sensors’ selectivity and sensitivity. Noise voltage across the sensor’s terminals (proportional to its resistance fluctuations) was recorded to estimate power spectral density. This function was an input data vector for LS-SVM (least squares – support vector machine) algorithm, which...
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Precipitation of calcium carbonate in the presence of rhamnolipids in alginate hydrogels as a model of biomineralization
PublicationThis paper reports the effects of rhamnolipids presence in the alginate hydrogel and CO32- solution, on the precipitation of CaCO3 in the Ca2+ loaded alginate hydrogel. Characteristics of the formed particles are discussed. Model conditions containing alginate hydrogel and rhamnolipids were used in order to mimic the natural environment of biomineralization in biofilms. It has been shown that rhamnolipids affect the characteristics...
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Diamond-Phase (Sp3-C) Rich Boron-Doped Carbon Nanowalls (Sp2-C): A Physico-Chemical And Electrochemical Properties
PublicationThe growth of B-CNW with different boron doping levels controlled by the [B]/[C] ratio in plasma, and the influence of boron on the obtained material’s structure, surface morphology, electrical properties and electrochemical parameters, such as -ΔE and k°, were investigated. The fabricated boron-doped carbon nanowalls exhibit activity towards ferricyanide redox couple, reaching the peak separation value of only 85 mV. The flatband...
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Rating mathematical models for first-pass of tracer in pCT lung studies
PublicationThis paper presents a comparison of model based on the Gauss function and the most commonly used Gamma-variate model in perfusion computed tomography (pCT) lung studies. It also verifies whether used model affects value of blood volume parameter. Three mean concentration-time curves were created from actual pCT measurements: arterial input function, blood vessels in lungs and lung parenchyma. On the basis of these mean curves we...
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Is sequential batch reactor an efficient technology to protect recipient against non-steroidal anti-inflammatory drugs and paracetamol in treated wastewater?
PublicationThe tested facility was a wastewater treatment plant (WWTP) in Swarzewo, where the wastewater treatment takes place in aeration chambers with activated sludge using sequential batch reactors (SBRs). The concentration of the following pharmaceuticals: ibuprofen, paracetamol, flurbiprofen, naproxen, diclofenac, and its metabolites 5OH-diclofenac and 4OH-diclofenac was tested in influents and effluents. Simultaneously, the conventional...
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Removal efficiency of phenol by ozonation process with calcium peroxide from aqueous solutions
PublicationPhenol has been introduced as a priority pollutant by the US Environmental Protection Agency. Advanced oxidation processes (AOPs) are one of the most efcient methods for removal of non-degradable organic pollutants in aqueous solutions. The removal efciencies of phenol and COD under optimal conditions pH=3, phenol concentration=5 mg/L, CaO2 concentration=0.025 mg/L, temperature 25 °C, 1 g/min ozonation rate and contact time=90...
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Aspects of pollution in Gdansk and gdynia Harbours at the coastal zone of the South Baltic Sea
PublicationOrganotin compounds (OTC), as well as metals, are toxic to many organisms. Even at very low concentrations OTC and metals can have several negative effects. The paper discusses key issues relating to the location of harbours in the coastal zone (including near the river mouths and semi-closed access to the sea) and the pollution of harbour sediments with heavy metals (e.g. zinc, copper, nickel and lead) and organotin derivatives...
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Effects of liquid phase modification on the performance of biotrickling filters
Open Research DataDataset presents the effects of liquid phase modification on the biotrickling filtration (BTF) performance of air polluted with toluene, ethylbenzene, xylene and styrene.
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The electrochemical response to glassy carbon electrode modification steps towards viral electrochemical immunosensor preparation
Open Research DataThe dataset contains the electrochemical measurements (CV/EIS) carried out for the consecutive steps of the glassy carbon GC electrode functionalization, in separate subfolders, as described. The cyclic voltammetry (CV) was conducted using a Palmsens 4 potentiostat/galvanostat system (Methrom, Autolab, Netherlands) in the standard three-electrode configuration,...
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Comparison of disk and tube methods for estimation of biostatic properties of polyurethanes based on synthetic poly[(R,S)-3-hydroxybutyrate
PublicationThe influence of novel aliphatic polyurethanes on growth of Staphyloccocus aureus (SA)in the around of polymer samples has been estimated by disk method. It was staed that the growth of SA was inhibited.The influence of polyurethanes on planctonic Staphyloccocus aureus was also pefrormed by tube method. In this test the slight decrease of bacteria concentration was noticed.
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Wettability of Horizontal Stainless Steel Tube by Nanofluid Droplets
PublicationThe goal of the present work was the experimental determination of the contact angle of three nanofluids, i.e. water-Al2O3, water-Cu and water-TiO2 on horizontal stainless steel tube of 1.6 mm OD. Of particular interest was the effect of nanoparticle concentration (0.01%, 0.1%, and 1% by weight) on droplet contact angle.
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Wettability of Horizontal Stainless Steel Tube by Nanofluid Droplets
PublicationThe goal of the present work was the experimental determination of the contact angle of three nanofluids, i.e. water-Al2O3, water-Cu and water-TiO2 on horizontal stainless steel tube of 1.6 mm OD. Of particular interest was the effect of nanoparticle concentration (0.01%, 0.1%, and 1% by weight) on droplet contact angle.
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Inner-shell fragmentation of molecules into neutral fragments in high-Rydberg states induced by soft X-ray excitation with pulsed-field ionization
PublicationIn the present communication, we will show the results of measurements probing the production of neutral high-Rydberg fragments at the K edges of the molecules containing oxygen and nitrogen atoms. The experiments were performed at the Gas Phase beamline of the Elettra synchrotron radiation laboratory (Trieste, Italy), exploiting a combined soft X-ray excitation with pulsed-field ionization and ion time-of-flight (TOF) spectrometry...
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Terbium Substituted Lanthanum Orthoniobate: Electrical and Structural Properties
PublicationThe results of electrical conductivity studies, structural measurements and thermogravimetric analysis of La1−xTbxNbO4+δ (x = 0.00, 0.05, 0.1, 0.15, 0.2, 0.3) are presented and discussed. The phase transition temperatures, measured by high-temperature x-ray diffraction, were 480 °C, 500 °C, and 530 °C for La0.9Tb0.1NbO4+δ, La0.8Tb0.2NbO4+δ, and La0.7Tb0.3NbO4+δ, respectively. The impedance spectroscopy results suggest mixed conductivity...
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Properties of Nasicon-based CO2 sensors with Bi8Nb2O17 reference electrode
PublicationPotentiometric CO2 sensors based on Nasicon (Na+ conductor, Na3Zr2Si2PO12) electrolyte, Bi8Nb2O17/Pt reference electrode and different sensing electrodes have been prepared. Besides the sensing electrode material, sensors differ from each other in the reference electrode preparation technique. The main aim of this study is to investigate sensor construction and electrode fabrication process influence on sensor properties. The optimal...
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Fe local structure in Pt-free nitrogen-modified carbon based electrocatalysts: XAFS study
PublicationThe paper presents a new results on the bonding environment (coordination number and geometry) and on oxidation states of Fe in nitrogen-modified Fe/C composites used as Pt-free catalysts for oxygen reduction in Direct Hydrogen Fuel Cells. Starting from glucose or fructose, two catalysts displaying different electrochemical performance were prepared and studied in the form of pristine powder and thin catalytic layer of electrode...
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Evaluation of Praseodymium and Gadolinium Doped Ceria as a Possible Barrier Layer Material for Solid Oxide Cells
PublicationIn this work, nanocrystalline layers based on the Pr, Gd co-doped CeO2 were investigated. For the preparation of thin layers, lowtemperature spray pyrolysis technique was used. Different stoichiometries of the layers were produced for comparison on polished sapphire substrates. The microstructure of the prepared thin layers was studied by scanning electron microscopy (SEM), energydispersive X-ray spectroscopy (EDS) and X-ray diffractometry (XRD)....
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Electro-chemo-mechanical properties in nanostructured Ca-doped ceria (CDC) by field assisted sintering
PublicationRecent investigations have shown that highly oxygen defective cerium oxides generate non-classical electrostriction that is superior to lead-based ferroelectrics. In this work, we report the effect of field-assisted spark plasma sintering (SPS) on electro-chemo-mechanical properties of calcium doped ceria (CDC). Nanometric powders of Ca.10 nm are rapidly consolidated to form polycrystalline nanostructures with a high degree of...
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Dissociative photo-double-ionization of the isoxazole molecules
PublicationThe five-membered heterocyclic rings are incorporated into a wide variety of structures that play a vital role in many biochemical processes. In particular, the isoxazole molecule appears in many bioactive compounds due to its unique ring structure that consists of one oxygen atom and one nitrogen atom at adjacent positions. The unique atomic composition and bond arrangement of isoxazole imply its specific electronic properties...
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Saccharides
PublicationSaccharides are widely distributed in nature as the major component of fruits and vegetables (primarily monosaccharides), milk and malt (mainly disaccharides), and grains (mostly polysaccharides). They are an important source of energy, structural material, as well as flavor and taste factors. Molecules of this class of compounds contain mainly carbon, hydrogen, and oxygen atoms; however, most natural saccha- rides do not have...
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Application of Eco-innovative Technologies of Nutrients Removal in Wastewater – Case Study BARITECH Project
PublicationEco-innovative technologies in wastewater treatment should provide not only stringent standards for the quality of treated wastewater but also ensure maximum recovery of energy and raw materials from wastewater. One of the ways to improve the removal efficiency of nitrogen and phosphorus compounds in existing conventional wastewater treatment plants is pretreatment of reject water generated during the mechanical...
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Sources of contamination in sediments of retention tanks and the influence of precipitation type on the size of pollution load
PublicationDensification of cities and urban population contributes to increased runoff and suspended solids and alteration of the urban water cycle. Nowadays, Blue-Green Infrastructure is promoted to increase a city’s resilience to floods; however, stormwater drainage systems, supported with retention tanks are still important in protecting urban areas against floods. Sediment accumulation in stormwater infrastructure relates to an issue...
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Optical Coherence Tomography for nanoparticles quantitative characterization
PublicationThe unique features of nanocomposite materials depend on the type and size of nanoparticles, as well as their placement in the composite matrices. Therefore the nanocomposites manufacturing process requires inline control over certain parameters of nanoparticles such as dispersion and concentration. Keeping track of nanoparticles parameters inside a matrix is currently a difficult task due to lack of a fast, reliable and cost effective...
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Impact of selected parameters of the fermentation process of wine and wine itself on the biogenic amines content: Evaluation by application of chemometric tools
PublicationThe demand for safer foods has promoted more research into biogenic amines (BAs) over the past few years, however, there are still some questions that remain unanswered. Despite the fact that BAs are present in wine and can cause toxic effect to the body, a shared regulation limiting the amounts of BAs in wine is still lacking. A detailed understanding of their presence in wine is also important for the food trade sector. Therefore,...
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ADAPTATION OF THE ACTIVATED SLUDGE TO THE DIGESTATE LIQUORS DURING THE NITRIFICATION AND DENITRIFICATION PROCESSES
PublicationThe activated sludge process of the digestate liquors after chemical separation was conducted using a 10 L lab-scale sequencing batch reactor (SBR) and a 0.50 m3 pilotscale SBR independently (with pH control). Due to the relatively high concentration of free ammonia (FA), clear inhibitory effects of the digestate liquors on the nitrifying bacteria were observed. The adaptation of the activated sludge to the toxicity was evaluated...